14. A toxicologist is studying the reaction used to produce mustard gas, S(CH2CH2CI)2, which is a blistering agent. At equilibrium, 0.409 M SCI2 and 0.788 M C¿H4 are present, and an equilibrium concentration of 0.233 M for S(CH2CH2CI)2 is achieved. Write an equilibrium expression for the given reaction and calculate the equilibrium constant. SCl, (g) + 2C,H, (g) + S(CH,CH,CI)2 (g)

14. A toxicologist is studying the reaction used to produce mustard gas, S(CH2CH2CI)2, which is a blistering agent. At equilibrium, 0.409 M SCI2 and 0.788 M C¿H4 are present, and an equilibrium concentration of 0.233 M for S(CH2CH2CI)2 is achieved. Write an equilibrium expression for the given reaction and calculate the equilibrium constant. SCl, (g) + 2C,H, (g) + S(CH,CH,CI)2 (g)

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter16: Solubility And Precipitation Equilibria

Section: Chapter Questions

Problem 70AP

See similar textbooks

Similar questions

Because calcium carbonate is a sink for CO32- in a lake, the student in Exercise 12.39 decides to go a step further and examine the equilibrium between carbonate ion and CaCOj. The reaction is Ca2+(aq) + COj2_(aq) ** CaCO,(s) The equilibrium constant for this reaction is 2.1 X 10*. If the initial calcium ion concentration is 0.02 AI and the carbonate concentration is 0.03 AI, what are the equilibrium concentrations of the ions? A student is simulating the carbonic acid—hydrogen carbonate equilibrium in a lake: H2COj(aq) H+(aq) + HCO}‘(aq) K = 4.4 X 10"7 She starts with 0.1000 AI carbonic acid. What are the concentrations of all species at equilibrium?
What is the law of mass action? Is it true that the value of K depends on the amounts of reactants and products mixed together initially? Explain. Is it true that reactions with large equilibrium constant values are very fast? Explain. There is only one value of the equilibrium constant for a particular system at a particular temperature, but there is an infinite number of equilibrium positions. Explain.
In a particular experiment, the equilibrium constant measured for the reaction, Cl2(g)+NO2(g)Cl2NO2(g), is 2.8. Based on this measurement, calculate AG° for this reaction. Calculate AG° using data from Appendix E at the back of the book and discuss the agreement between your two calculations.
Write the expression for the equilibrium constant and calculate the partial pressure of CO2(g), given that Kp is 0.25 (at 427 C) for NaHCO3(s) NaOH(s) + CO2(g)
Consider the system 4NH3(g)+3O2(g)2N2(g)+6H2O(l)H=1530.4kJ (a) How will the concentration of ammonia at equilibrium be affected by (1) removing O2(g)? (2) adding N2(g)? (3) adding water? (4) expanding the container? (5) increasing the temperature? (b) Which of the above factors will increase the value of K? Which will decrease it?
The creation of shells by mollusk species is a fascinating process. By utilizing the Ca2+ in their food and aqueous environment, as well as some complex equilibrium processes, a hard calcium carbonate shell can be produced. One important equilibrium reaction in this complex process is HCO3(aq)H+(aq)+CO32(aq)K=5.61011 If 0.16 mole of HCO3 is placed into 1.00 L of solution, what will be the equilibrium concentration of CO32?
Use the solubility product constant from Appendix F to determine whether a precipitate will form if 10.0 mL of 1.0 106 M iron(II) chloride is added to 20.0 mL of 3.0 104 M barium hydroxide.
Some barium chloride is added to a solution that contains both K2SO4 (0.050 M) and Na3PO4 (0.020 M). (a) Which begins to precipitate first: the barium sulfate or the barium phosphate? (b) The concentration of the first anion species to precipitate, either the sulfate or phosphate, decreases as the precipitate forms. What is the concentration of the first species when the second begins to precipitate?
Write a chemical equation for an equilibrium system that would lead to the following expressions (ad) for K. (a) K=(PH2S)2 (PO2)3(PSO2)2 (PH2O)2 (b) K=(PF2)1/2 (PI2)1/2PIF (c) K=[ Cl ]2(Pcl2)[ Br ]2 (d) K=(PNO)2 (PH2O)4 [ Cu2+ ]3[ NO3 ]2 [ H+ ]8
. The solubility product of iron(III) hydroxide is very small: Ksp=41038at 25 °C. A classical method of analysis for unknown samples containing iron is to add NaOH or NH3. This precipitates Fe(OH)3, which can then be filtered and weighed. To demonstrate that the concentration of iron remaining in solution in such a sample is very small, calculate the solubility of Fe(OH)3in moles per liter and in grams per liter.
When 250 mg of SrF2, strontium fluoride, is added to 1.00 L of water, the salt dissolves to a very small extent. SrF2(s)Sr2+(aq)+2F(aq) At equilibrium, the concentration of Sr2+ is found to be 1.03 103 M. What is the value of Ksp for SrF2?
. Write the balanced chemical equation describing the dissolving of each of the following sparingly soluble salts in water. Write the expression for K for each process. a. AgIO3(s) c. Zn3(PO4)2(s) b. Sn(OH)2(s) d. BaF2(s)