*14) What is the predicted product of the reaction shown? Give detailed mechanism Solution with reaction mechanism with explanation needed. don't give Handwritten answer NH₂OH H2SO4 ONH2 NOH NHOH HO NH2 HO OH || IV A) (B) II OH C) III D) IV E) V
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- Provide the structure(s) of the expected major organic product of the reaction shown. 1) Disiamylborane 2) H₂O₂, NaOH OI O II ||| O IV OV CH3CH₂C(CH3)2C=CH OH OH xx xo IV(i) OEt OEt 1) NaOEt 2) H3O* workup W 1) NaOEt 2) Br V Compound W can be synthesised in an excellent yield via an intramolecular Claisen reaction of 1,6-diester V. Draw the structure of product W and provide detailed reactions mechanisms to account for its formation. (ii) Draw the product X which would form upon the alkylation reaction of W with the reagents shown.biackboard.gwu.edu/webapPps/assessment/feview/review.jsprattempld Select the major product of the reaction below. 1) TIPSCI, Et3N 2) Na 3) 03, then CH3SCH3 4) CH3CH2LI, then H30* 5) Bu4N* F', H2O CI Selected Answer: Он HO Answers: он он он OH OH OH он Select the major product of the reaction below. The answer is there, but please explain step by step.
- 9. Write structural formulas for the major organic product(s) for the following reactions. Be sure to indicate stereochemistry when relevant. (CH;CH,CH,),CuLi (a) Cl Br PAL2 (b) HO (c) CH;CH,CH,CH,OH C,H5MgBr 10. Propose a reasonable mechanism for the following reaction Be sure to include all intermediates. (transition states are not necessary) Br Br hv CH3-CH=C(CH3)2 + Br, ČH,-CH=C(CH3)2 CH2=CH–Ċ(CH3)2 11. Indicate how each of the following compounds could be prepared using the given starting material CH;CH,CH,CH3 CH;CH,CH,CH,Br CH;CH,CH,CH3 H,C=CH-CH=CH2 Br CH;CHCH,CH3 CH;CH=CCH,CH3 CH35 a) For each of the reactions below, describe a suitable reaction mechanism, stating the reaction conditions and naming the major productsi) Nitrobenzene and Chloromethaneft) 2-chloro-2-methyl propane and aqueous potassium hydroxide.iii) Propanone and hydrogen cyanide.iv) iodoethane and sodium hydroxide in ethanol.b) i) Discuss the bonding and extra.stability of benzene,ii) Using suitable examples, compare the reactivity of benzene and ethane,Predict the major products of the following reactions. (a) the tosylate of cyclohexylmethanol + excess NH3(b) n-butyl tosylate + sodium acetylide, H¬C‚C:- +Na
- The reaction below is the addition of HCl to 3-methylenecyclohex-1-ene. CH2 + HCI (i) Draw and name the kinetic and thermodynamic products structures of this reaction. (ii) Show the mechanism of reaction, while explaining the kinetic and thermodynamic preference of the reaction.It is not uncommon for organic chemists to prepare acetals by an exchange-type process known as transacetalization. Predict the product(s) and show the mechanism for the transacetalization reactions below.9. (a) With the help of orbital correlation diagram predict the conditions of 4+2r system. (b) Using PMO approach, discuss the reaction conditions for 4x electrocyclic reaction. (c) What are 1,3-dipolar cycloaddition reactions? Give examples. 10. Predict the product under the given reaction conditions and propose mechanism. C (b) A OMe O OMe OMe A in Decane
- (b) Predict the product in the following reaction under the given reaction conditions: ond (a) CH f i) n-Buli, -80°C I)NH,CI CH₂Cl₂, Meli UNIT-IV 7. Giving justification, predict the product(s) (major and minor; if any) in the following reactions : C₂H5OH/ OC₂H5Q1) suggest a suitable mechanisms for the following organic fon H₂O/H a) penta-1-ene sec-pentyl alcohol H₂SO₂ b) 4-methylpent-2-ene + Iso butane 2,4,5,7-tetramethyloctane FeCl, c) Benzoic acid + Cl₂ 3-Chloro Benzoic acid H₂SO d) cyclo pentanol. cyclo pentene e) nitrobenzene + HNO, H₂SO 1-3dinitrobenzeneGive the major organic product(s) for each of the following reactions (a) + H2 1. (CF3CO0)2Hg. CH3OH (b) 2, NABH4