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- Which hydroxyl groups in the following reactions would require protection? (a) (b) CN Br Mg(s) НО -MgBr НО. NaCN НО. HỌ (c) (d) OH 1. NaH NaBH4 Ph 2. CeH5CH,I Ethanol HO НО НО HOMicrosoft Edge X + een%20kaur/Downloads/1015MSC%20T1%202022%20Lab%20Workbook.pdf CD Page view A Read aloud TAdd text Draw Highlight 4. Tylenol also is an analgesic often taken by people allergic to aspirin. The active ingredient is acetaminophen. HO -NH FO H3C Would acetaminophen give a positive phenol test? (Y/N). Does this compound contain the ester functional group? If not, what functional group(s) is/are present? 10 S1. Refer to the dehydration reaction given below involving 2-butanol and answer the questions that follow. OH H,SO, CH;-CH,-CH-CH3 R + S i) The boiling point of 2-butanol is higher than butane. Give a reason for the difference in the boiling points of the two compounds. ii) The dehydration of 2-butanol yields two products R and S. Write the structure of the two products formed. Identify the major product. Explain the reason for your choice of the major product. 2. Indicate which is the stronger acid. Explain your choice clearly. H3C-CH-CH2 OH H3C-CH2 CH2OH or F 3. Give the IUPAC names of molecules CH3 H3C-CH-CH2 CH-CH-CH3 Br 4. A student was asked to prepare an alkene X in high yield using any alcohol as starting material CH3 CH;-C- -CH=CH2 CH3 X He chose 3, 3-dimethylbutan-2-ol (XI) and carried out a dehydration reaction. He was however horrified to note that the only alkene obtained was XII. CH3 ОН CH3 conc. H,SO4 CH-CH3 CH;-C=C-CH3 heat CH3 CH3 XI XII i) Explain what went wrong…
- (a) Answer the following questions based on the reaction scheme below. Jawab soalan berikut berdasarkan rajah tindak balas di bawah. H,SO, 180°C R OH+ Δ U NH, (i) State reagent Q. Nyatakan reagen Q. (ii) Draw the structural formula for compounds R, T, U and W. Lukiskan formula struktur bagi sebatian R, T, U dan W. PCI,HgSO4 H2SO4, H20 1T (1) Br H2O2, NaOH 10 NaNH2 BH3, THE H =H 1S NH3 H20 HCI (1 equiv.) diethyl ether 1V 1W Br2 (m) MgBr (H,C=CH),CULI NaOCI ТСРВА > 1X 1Y > 1Z CH3COOH 1AA diethyl ether SoCI2, pyridine diethyl ether 1ABWith the molecular formula C4H8O , I ask you to draw 3 molecules: an aldehyde, a ketone and an enol.For each molecule, you must: a) Complete detailed Lewis structure;b) Make the 3D structure respecting the connection angles;c) Determine which intermolecular interactions are present if you glue 2 twin molecules together (2 aldehydes together, 2 ketones together, 2 enols together, therefore 3 situations to analyze).
- Predict the products of the following acid-base reactions. If the equilibrium would not result in the formation of appreciable amounts of products, you should so indicate. In each case label the stronger acid, the stronger base, the weaker acid, and the weaker base: (a) CH3CH=CH2 + NANH2 (d) CH3C=C: + CH;CH2OH → (e) CH3C=C:- + NH¾CI – | (b) CH;C=CH + NaNH2 (c) CH3CH2CH3 + NANH2 → | HASa) If the pH value of an aqueous solution of trimethylamine [(CH3) 3N] is 10.75, what should be the molarity of this solution? (CH3) 3N + H2O ↔ (CH3) 3NH + + OH-, Kb = 6.3 × 10-5 b) What will be the pH of the solution prepared by dissolving 8.35 g of aniline hydrochloride (C6H5NH3 + Cl-) in 750 mL of 0.215 M aniline (C6H5NH2)? Is this solution an effective buffer? Explain (Kb = 7.4 × 10-10 for aniline, C: 12.0 g / mol, H: 1.0 g / mol, N: 14.0 g / mol, Cl: 35.4 g / mol) .a) If the pH value of an aqueous solution of trimethylamine [(CH3)3N] is 10.75, what should be the molarity of this solution? (CH3)3N + H2O ↔ (CH3)3NH+ + OH-, Kb = 6,3 × 10-5 b) What will be the pH of the solution prepared by dissolving 8.35 g of aniline hydrochloride (C6H5NH3+Cl-) in 750 mL of 0.215 M aniline (C6H5NH2)? Is this solution an effective buffer? Explain (Kb = 7,4 × 10-10 for aniline, C: 12.0 g / mol, H: 1.0 g / mol, N: 14.0 g / mol, Cl: 35.4 g / mol) .
- Identify (A) in the following reaction. 2H2 Pt (A) KMNO4 Warm conc. || С — С — о—н |CO,H + HO CO2H cis-cyclo hexane 1,2-dicarboxylic acid (a) (b) (c) (d)-COH (acid) &H (aldehyde) Ar-H (aromatic) (C=C-H, vinylic OH (alcohol or phenol) X-C-H (X= halogen or oxygen) Ar-C-H (benzylic) CH 10.0 (C-C-C-H, allylic H on saturated C, base position 9.0 8.0 44 7.0 4.3 30 20 10 0 6.0 In this ¹H NMR spectrum the blue floating peaks are enlargements of the peaks to their right. 4.2 ppm Hz 5.0 1 4.0 10-13 9-10 3.0 6-8.5 4.6-5.7) 1-5 3-4.5 2-2.7 2-2.7 1.6-1.9) .8-1.6 l 1.75 1.70 1.65 2.0 1.0 0.0 Which compound is most likely to have given rise to this spectrum?1- The following compounds have similar molecular weights. Which has the highest boiling point? A) CH3CH=O В) С.Н,ОН C) CH3OCH3 D) CH:CH:CHз 2- Which of the following is not an electrophile? A) C2HsOC2Hs В) BF; C) [CH3]3Ce) D) HỌC 3- What is a group of atoms bonded to a carbon of an organic compound called? A group of atoms bonded to a carbon of an organic compound is called a functional group. There are a variety of functional groups such as hydroxy (-OH), carboxyl (CO0-), and amine (NH22). 4- Give any branch of chemistry that is widely studied? Chemistry is the study of matter - anything that has mass and volume. This central science looks into the physical and chemical properties of matter and how these properties are connected to the structure of matter in an atomic or molecular level. The changes involved in matter are also looked at be it physical change or chemical change. 5- What are the physical properties of organic compounds? Organic compounds are known as the compounds…