1. Determine the oxidation number of the elements in each of the following compounds:

Introductory Chemistry: A Foundation
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Chapter18: Oxidation–reduction Reactions And Electrochemistry
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1. Determine the oxidation number of the elements in each of the following
compounds:
а. Н2СОЗ
b. N2
с. Zn(OH),?-
d. NO2
е. LiH
f. Fe:O4
Transcribed Image Text:1. Determine the oxidation number of the elements in each of the following compounds: а. Н2СОЗ b. N2 с. Zn(OH),?- d. NO2 е. LiH f. Fe:O4
I. Oxidation Number method
(valence - Change)
I. Half -Reactions method
(Jon- Flectron)
Fe z O3 (S)
CO
9)
Fe cs) + COz Cg)
(5)
+ COz
• Ass ign oxidation Numbers
- Assign oxidation Numbers
-6
12 -2
+4 4
+6
-6
+2 -2
+4 -4
CO (6)
Fe cs) t Casy)
CO 6)
Fe (S)
+ COz G)
:. Fe : +3
C 12
ře = 0
C: +4
:. Fe : +3
C: +2
fe : 0
C : +4
Determine the change in ON
Determine reduction /oxidation
Fe : + 3
gained
3 e
:. reduction
-3
Fe :
(per atom)
+ 3
+2
: oxidation
last
(per atom)
+ス
-- +4
+ス
+ +4
Note the change in ON
Separate into half-reactions, balance redox atoms
-3
toe
2 fe (s)
(5)
Fe z O3 (S)
CO (9)
ー Fe cs) t CO2 G)
+2
Balance the change in
Balance the e
ON
= -6
-3 x(2
Fe 2 03
+ be
(5)
2 Fe (5)
Fe 2 03 (5)
Có (9)
Fe' cs) + CO2 Cg)
+ CO2
be
O *3
+2 x3
: +6
• Apply coe fificients in equation
Get the overall reaction
+ 3 CO (g)
→ 2 Fe es) + 3 CO2 Cg)
2 Feen t 3 COz egs + be
ャ
Transcribed Image Text:I. Oxidation Number method (valence - Change) I. Half -Reactions method (Jon- Flectron) Fe z O3 (S) CO 9) Fe cs) + COz Cg) (5) + COz • Ass ign oxidation Numbers - Assign oxidation Numbers -6 12 -2 +4 4 +6 -6 +2 -2 +4 -4 CO (6) Fe cs) t Casy) CO 6) Fe (S) + COz G) :. Fe : +3 C 12 ře = 0 C: +4 :. Fe : +3 C: +2 fe : 0 C : +4 Determine the change in ON Determine reduction /oxidation Fe : + 3 gained 3 e :. reduction -3 Fe : (per atom) + 3 +2 : oxidation last (per atom) +ス -- +4 +ス + +4 Note the change in ON Separate into half-reactions, balance redox atoms -3 toe 2 fe (s) (5) Fe z O3 (S) CO (9) ー Fe cs) t CO2 G) +2 Balance the change in Balance the e ON = -6 -3 x(2 Fe 2 03 + be (5) 2 Fe (5) Fe 2 03 (5) Có (9) Fe' cs) + CO2 Cg) + CO2 be O *3 +2 x3 : +6 • Apply coe fificients in equation Get the overall reaction + 3 CO (g) → 2 Fe es) + 3 CO2 Cg) 2 Feen t 3 COz egs + be ャ
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