1. (30 points) Provide a complete, arrow-pushing mechanism to justify all the products in the reaction below. Label your mechanism as SN1, SN2, E1, or E2. Br NaOMe major + minor + minor
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- 2. (10 points) Complete the reaction scheme below. Show all reagents and intermediates. No reaction is a possible answer. 1) CH;CH,MgBr CH,OH H+ (excess) но 2) H,O*, H20 в A OCH3. Use to curved arrow notation, propose a mechanism for the following reaction and state whether it is either SN1, E1, SN2, or E2. Give the IUPAC names of all organic reactants and products.5.
- Predict the major product of the given reaction and then draw a reasonable mechanism for the product formation using appropriate curved arrow notation. Part 1: OH H2SO4 (aq) view structure Part 2 out of 4 H,0 H,SO4 HSO, HO finish structure . draw structure . H;O*(3) Mechanism. Provide the mechanism for the following reaction. HO OH Он |-0 HO Он NaOH, Н2О но HO Он HO Он3. Show a mechanism for the following reaction. Q.XX NO₂ NO₂
- Please Explain.(a) Provide a detailed mechanism for the reaction shown below. Br2/H20 HO. Br1.70 An a,ß-unsaturated ketone reacts with a conjugated Wittig reagent to produce a relatively highly strained bicyclic compound. Draw the complete, detailed mechanism for this reaction. (A key intermediate has been provided.) H3C- `CH3 + (C6H5)3PO + H3C
- iii) 10. For each of the following reactions, provide the structure of the major product and circle the predominant mechanism. Indicate the stereochemistry where necessary. VII) E1 E2 SN1 SN2 E1 E2 SN1 SN2 NaSH DMF H* CH3OH Br (CH3)3COK (CH3)3COH OH iv) HBr viil) E1 E2 E1 E2 SN1 SN2 SN1 SN2iii) vii) 10. For each of the following reactions, provide the structure of the major product and circle the predominant mechanism. Indicate the stereochemistry where necessary. E1 E2 SN1 SN2 E1 E2 SN1 SN2 NaSH DMF H* CH₂OH Br (CH3)3COK (CH3)3COH OH iv) HBr viil) E1 E2 SN1 SN2 E1 E2 SN1 SN2Draw the major organic product generated in the reaction below. Pay particular attention to regio- and stereochemical detail. CH₂CH₂CH3 НО. Provide a detailed, step-by-step mechanism for the reaction shown below. 1.03 2. (CH₂)₂S Br₂