1. 2. BF3 a = Proton transfer b = Lewis acid/base c = Radical chain substitution 1. ICI 2. BF3 Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers. d = Electrophilic addition g= SN1 Nucleophilic substitution h = SN2 Nucleophilic substitution e = E1 Elimination f = E2 Elimination

1. 2. BF3 a = Proton transfer b = Lewis acid/base c = Radical chain substitution 1. ICI 2. BF3 Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers. d = Electrophilic addition g= SN1 Nucleophilic substitution h = SN2 Nucleophilic substitution e = E1 Elimination f = E2 Elimination

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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1. 2. BH3 a Proton transfer b = Lewis acid/base 1. N(CH3)3 2. NaOEt EtOH CH3 H₂B-N-CH3 CH3 + NaCl + e Electrophilic addition f = E1 Elimination g = E2 Elimination. HOEt Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - j for your answers. h = SN1 Nucleophilic substitution i = SN2 Nucleophilic substitution j = Electrophilic aromatic substitution 12a
1. 2. CH3 H₂C+B -Br CH3 a Proton transfer b = Lewis acid/base c = Radical chain substitution 1. 2. ICI C₂H5 N-C₂H5 C₂H5 d = Radical chain addition Electrophilic addition e = f = E1 Elimination C₂H5 +1 H-N-C₂H5 Br C₂H5 g = E2 Elimination h = SN1 Nucleophilic substitution i = SN2 Nucleophilic substitution Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers.
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(10) The following can undergo 1,2- or 1,4-addition reactions. Predict the major organic product from each reaction. 1. LiAlH4 2. H+ 1. CH3S- +Na 2. H+ 1. KCN 2. H+ 1. (CH3CH₂)2CuLi 2. H 1. CH3CH₂MgCl 2. H+
1. 2. CH3 a 1. www 2. CH3 + Br a = Proton transfer b = Lewis acid/base c = Radical chain substitution HCI مار Na benzene, reflux CH₂ d CI d Radical chain addition e = Electrophilic addition f = E1 Elimination 4 HO-CH + NaBr Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers. g = E2 Elimination h = SN1 Nucleophilic substitution i = SN2 Nucleophilic substitution
1. 2. CH3O. OCH3 8 HO a = Proton transfer b = Lewis acid/base c = Radical chain substitution d = Radical chain addition AICI 3 CH3 НО. ZnCl₂ CH3O LOCH3 no. OH e = Electrophilic addition f = E1 Elimination g = E2 Elimination H₂O h = SN1 Nucleophilic substitution i = SN2 Nucleophilic substitution j= Electrophilic aromatic substitution Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - j for your answers.
1. 2. H₂C 1. MeO 2. -CH3 H₂O a = Proton transfer b = Lewis acid/base c = Radical chain substitution H3PO4 80° MeO CH3 H₂COM₂ CH3 d = Radical chain addition e = Electrophilic addition f = E1 Elimination H₂O Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers. g = E2 Elimination h = SN1 Nucleophilic substitution i = SN2 Nucleophilic substitution
Question 3
1. 2. Ph 1. Ph OH a Proton transfer b = Lewis acid/base c = Electrophilic addition 2. + Na CN NMe₂ DMF H₂SO4 Ph Ph H3C H CH3 H CN OH NM²₂ Tamoxifen anti (brest) cancer drug Ph d E1 Elimination = e = E2 Elimination Ph NMe₂ The rections above involve synthesis or reactions of alcohols and ethers. Identify the mechanism by which they proceed from among the mechanisms listed. Use the letters a- g for your answers. f = SN1 Nucleophilic substitution gSN2 Nucleophilic substitution
Criteria for satisfactory score Reactants, products, and reagents that complete a reaction scheme must specific compounds, not generic categories. Reagents and structures must be valid Lewis structures. Tasks Complete the synthetic sequences by drawing products/substrates/reagents in empty spaces in reactions below. 1. t-BUOK, heat 2. Br2 (1 equiv) methanol (solvent) Br 1. O3 2. Me2S 1. Hg(OAc)2, H2O 2. NABH4
Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers.