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1) In the following reactions, give the nature and possibly the stereochemistry of A1, A2 and B and justify the proportions obtained. CI OH majority isomere of A1 KOtBu ΑΙ + B DMSO H2SO4 equimolar mixture ΑΙ + A2

1) In the following reactions, give the nature and possibly the stereochemistry of A1, A2 and B and justify the proportions obtained. CI OH majority isomere of A1 KOtBu ΑΙ + B DMSO H2SO4 equimolar mixture ΑΙ + A2

Organic Chemistry
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter9: Nucleophilic Substitution And Β-elimination
Section: Chapter Questions
Problem 9.31P
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1) In the following reactions, give the nature and possibly the stereochemistry of A1, A2 and B and justify the proportions obtained. 4 1=3 |=1 CI ull OH KOtBu 3 DMSO H₂SO4 majority A1 A1 + 2)When the first compound is treated with MeONa in methanol, compounds A1 and B are also obtained, as well as a higher molecular weight compound C, which has a higher molecular weight. B are also obtained as well as a higher molecular weight compound C whose 1H NMR spectrum is given below. Justify the formation of C. 2 PPM equimolar mixture + isomere of A1 1=3 mobilie B A2 1=3 1=3 1 1=3 O
Transcribed Image Text:1) In the following reactions, give the nature and possibly the stereochemistry of A1, A2 and B and justify the proportions obtained. 4 1=3 |=1 CI ull OH KOtBu 3 DMSO H₂SO4 majority A1 A1 + 2)When the first compound is treated with MeONa in methanol, compounds A1 and B are also obtained, as well as a higher molecular weight compound C, which has a higher molecular weight. B are also obtained as well as a higher molecular weight compound C whose 1H NMR spectrum is given below. Justify the formation of C. 2 PPM equimolar mixture + isomere of A1 1=3 mobilie B A2 1=3 1=3 1 1=3 O
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