Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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PARTS 1, 2, 3 please

The ghost of J. C. Maxwell is hired to help the Acme Corporation convert thermal heat into useful work. He acts using the following cycle involving one mole of ideal gas in a volume V that is divided into two equal parts by a wall with a trapdoor under his control. The device is in contact with a thermal reservoir at temperature T, and so all steps are isothermal. By letting molecules pass only from left to right (a), he accumulates all the molecules in the right side of the device (b). He then replaces the partition with a piston coupled to a reversible work source (c), and expands the gas to its original volume (d). a) b) v/2 v/2 d) (1) Analyze each step of this process. (2) Calculate changes in energy and entropy of the gas and the surroundings, any flow of heat, and any work done. (3) For the overall process, how much useful work has been extracted? (4) Where did the energy to do the work come from? (5) Does this device violate the second law of thermodynamics? (6) Should you buy stock in the Acme Corporation?
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Transcribed Image Text:The ghost of J. C. Maxwell is hired to help the Acme Corporation convert thermal heat into useful work. He acts using the following cycle involving one mole of ideal gas in a volume V that is divided into two equal parts by a wall with a trapdoor under his control. The device is in contact with a thermal reservoir at temperature T, and so all steps are isothermal. By letting molecules pass only from left to right (a), he accumulates all the molecules in the right side of the device (b). He then replaces the partition with a piston coupled to a reversible work source (c), and expands the gas to its original volume (d). a) b) v/2 v/2 d) (1) Analyze each step of this process. (2) Calculate changes in energy and entropy of the gas and the surroundings, any flow of heat, and any work done. (3) For the overall process, how much useful work has been extracted? (4) Where did the energy to do the work come from? (5) Does this device violate the second law of thermodynamics? (6) Should you buy stock in the Acme Corporation?
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