07 0.08 0.09 0.1 0.11 0.12 0.13 0.14 0.15 0.16 0.17 0.18 0.19 0.2 0.21 0.22 0.23 3.62 Filename Author JEOLO Experiment Sample Id Solvent Actual Start Time Revision Time Data Format Din Size X_Domain Din Title Din Units Dimensions Spectrometer Field Strength X_Aoq Duration X Domain X Freq X_Offset x Points X Prescans X_Resolution X Sweep X Irr Domain Irr_ Freq IEF Offset Tri Domain Tri Freq Tri offeet Blanking Clipped Scans Total Scans Sweep_Clipped Relaxation Delay Comp sample 4 PROTO delta - - proton.jxp Comp sample 4 CHLOROFORM-D - 30-SEP-2021 16:18:3 - 30-SEP-2021 16:05:3 1D COMPLEX - 26214 - Proton - Proton - [(ppm) J-ECZ4008/11 -9.389766 [7] (400 [ME -4.37256192[*] - Proton -399.78219838) - 5(ppm) -32768 -0 -0.22869888(N) -7.4940048[k] -5.99520384[k] -399.78219838] - Proton - 5(ppm) - Proton - 399.78219838) <- 5(ppm) <-2[us] = FALSE -32 -32 <- 4[0]

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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4-tert-butylcyclohexanol

S(ppm)
JEOLO
Filename
Author
Experiment
Sample_Id
Solvent
Actual_Start_Time
Revision Time
- Comp sample 4_PROTO
- delta
- proton.jxp
- Comp sample 4
- CHLOROFORM-D
- 30-SEP-2021 16:18:3
- 30-SEP-2021 16:05:3
Data Format
Din Size
X Domain
Din Title
Dim Unita
Dimenaions
Spectrometer
- 1D COMPLEX
- 26214
- Proton
- Proton
- [ppm)
- JNM-ECZ400S/L1
Field Strength
X_Aoq Duration
X_Domain
X_Freq
x Offset
X_Pointa
x_Prescans
X_Resolution
X_Sweep
X_Sveep_ClipPped
IEE Domain
Irr Freq
Irr offset
Tri Domain
Tri Preq
Tri Offset
Blanking
Clipped
Scana
- 9. 389766 (2) (400 (M
- 4.37256192[a)
- Proton
- 399. 78219838 (MH)
- 5(ppm)
- 32768
- 0.22869888[Hz)
- 7.4940048 (kHa)
- 5.99520384 (kHz)
- Proton
- 399. 78219838 (Mz)
- S(ppm)
- Proton
- 399. 78219838 (MEz)
- Stppm]
- 2[us)
- FALSE
- 32
- 32
Total_Scans
Relaxation Delay
Recve Gain
Tanp Get
x 90 Width
X
X Acq Time
X_Angle
X_Atn
* Pulse
Irr Mode
Tri Mode
Dante Loop
Dante Presat
Decimation_Rate
Experiment Path
Initial Wait
Phase
- 4[0]
- 42
- 23[dc)
- 6.097 (ua)
- 4.37256192[8]
- 45(deg)
- 2[dB]
- 3.0485 (us)
- off
- off
- 400
- PALSE
êthanol
impurity
- e: \Program Piles\JE
- (0, 90, 270, 180, 1
Presat Time
Presat Time Flag
Ralaxation Delay Cale = O(e)
Relaxation Delay Temp- 4(]
Repatition Time
- FALSE
= 8.37256192 (s]
4.0
3.0
2.0
1.0
X: parts per Million : Proton
abundance
0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0,1 0.11 0.12 0.13 0.14 0.15 0.16 0.17 0.18 0.19 0.2 0.21 0.22 0.23
3.62
Transcribed Image Text:S(ppm) JEOLO Filename Author Experiment Sample_Id Solvent Actual_Start_Time Revision Time - Comp sample 4_PROTO - delta - proton.jxp - Comp sample 4 - CHLOROFORM-D - 30-SEP-2021 16:18:3 - 30-SEP-2021 16:05:3 Data Format Din Size X Domain Din Title Dim Unita Dimenaions Spectrometer - 1D COMPLEX - 26214 - Proton - Proton - [ppm) - JNM-ECZ400S/L1 Field Strength X_Aoq Duration X_Domain X_Freq x Offset X_Pointa x_Prescans X_Resolution X_Sweep X_Sveep_ClipPped IEE Domain Irr Freq Irr offset Tri Domain Tri Preq Tri Offset Blanking Clipped Scana - 9. 389766 (2) (400 (M - 4.37256192[a) - Proton - 399. 78219838 (MH) - 5(ppm) - 32768 - 0.22869888[Hz) - 7.4940048 (kHa) - 5.99520384 (kHz) - Proton - 399. 78219838 (Mz) - S(ppm) - Proton - 399. 78219838 (MEz) - Stppm] - 2[us) - FALSE - 32 - 32 Total_Scans Relaxation Delay Recve Gain Tanp Get x 90 Width X X Acq Time X_Angle X_Atn * Pulse Irr Mode Tri Mode Dante Loop Dante Presat Decimation_Rate Experiment Path Initial Wait Phase - 4[0] - 42 - 23[dc) - 6.097 (ua) - 4.37256192[8] - 45(deg) - 2[dB] - 3.0485 (us) - off - off - 400 - PALSE êthanol impurity - e: \Program Piles\JE - (0, 90, 270, 180, 1 Presat Time Presat Time Flag Ralaxation Delay Cale = O(e) Relaxation Delay Temp- 4(] Repatition Time - FALSE = 8.37256192 (s] 4.0 3.0 2.0 1.0 X: parts per Million : Proton abundance 0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0,1 0.11 0.12 0.13 0.14 0.15 0.16 0.17 0.18 0.19 0.2 0.21 0.22 0.23 3.62
What is the ratio of cis- : trans-isomers in the product mixture?
Is the ratio an enantiomeric ratio (er) or a diastereomeric ratio (dr)?
One of the reasons that the spectral signals are well-resolved is that the products are
conformationally locked and cannot “ring flip". What structural feature is responsible for this
effect, and why?
Transcribed Image Text:What is the ratio of cis- : trans-isomers in the product mixture? Is the ratio an enantiomeric ratio (er) or a diastereomeric ratio (dr)? One of the reasons that the spectral signals are well-resolved is that the products are conformationally locked and cannot “ring flip". What structural feature is responsible for this effect, and why?
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