The purpose of this investigation is to burn selected alcohols of different molecular structure in a controlled environment to compare the magnitude and rates of energy release.
Fuels are any kind of substance that, when burnt, produces chemical or nuclear energy that can be used for work. More accurately, fuels may be defined as a naturally occurring or artificially prepared combustible carbonaceous material (Palanna, 2009). One of the most common fuels that is still used today is charcoal. Charcoal is the remains of burnt wood which was discovered to be a good fuel source and was used to melt metals.
When fuels are burnt the majority of the energy released was stored within the weak double bond of molecular oxygen found in the fuel.
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This is why the control test scored an enthalpy result of 594.26 which is approximately half of the result of the insulated pentanol tests which was 1179.76. Furthermore, the insulated tests had an aluminium plate covering the roof of the design which both contained the heat from escaping and reflected the radiation energies. This significantly increased the amount of heat pooling at the top of the shroud which had nothing else to do but heat the water directly adjacent to it, resulting in a higher …show more content…
The first way to improve the result obtained would be the use of an insulator that can contain a higher level of heat than the plain aluminium and steel shrouds. The original design concept incorporated this by wrapping the steel shroud with glass fibre and having small pipes with holes cut into the fibre for gasses to escape. It was estimated that the original design would yield a percentage of heat trapped to be equal to ~50%. The second factor that could slightly improve the outcome is the use of a fume cupboard. This would completely eliminate the chance of dynamic forces affecting the reaction while still allowing the reaction plenty of oxygen to
We heated the hydrates in separate fume hoods with two Bunsen burners for ten minutes each.
It was desired to compare a theoretical value of enthalpy of combustion to a literature value. To do this, the theoretical value was calculated using a literature value for the heat of sublimation of naphthalene, the heat of vaporization of water and average bond energies, given in Table 1 of the lab packet.1 Equations (1) and (5) were used to calculate the theoretical enthalpy of combustion of gaseous naphthalene, where n was the number of moles, m was the number of bonds, and ΔH was the average bond energy:
Table 1 summarises the results from the primary data collected. Figure 5 indicates there is a linear relationship between the molecular weight and heats of combustion. Figure 6 compares the heats of combustion of the primary data, the accepted values and values calculated from the bond dissociation energy. Figure 6 compares the heat of combustion values identified by the bond dissociation energy calculations, the accepted values and experimental values when 80g of water is heated by 10°C. The bond dissociation energies do not take into account the hydrogen bonding and the accurate energy required to change the tested alkanol from an aqueous state to a gaseous state. The experiments done to identify the accepted values were conducted
An alcohol dehydration reaction is useful for synthesizing alkenes. Through the use of an acid catalyst, an alcohol is protonated and then dehydrated by the loss of a water molecule. This dehydration step results in a carbocation, and deprotonation by a base results in a final alkene product. In this experiment, 4-methylcyclohexene was obtained with a 32% yield. The theoretical yield of the product was 6.3 grams, but the actual yield of the product was 2.0 grams. A low percent yield of product could be attributed to systematic errors. An improperly tared scale, an inaccurately lined graduated cylinder, or a tiny crack in glassware could result in less than desirable product yields.
Introduction: long ago the government banned the ability to make alcohol. This has caused a huge uproar which then people started to boot legging, as more and more people started to drink in the safety of their own homes. After the government saw how people were protesting this new law, they decided that they should left the ban. Since then people were able to drink in public, which in return has created another issue, now that they are drunk at a bar, how do they get home. Rather than taking the safe option and utilize some of the state and local programs and call a tow truck, the Driver chooses to just drive how drunk. They think that it’s ok, since they do not have their full mind.
The impact of this error could be reduced if the soot was cleaned from the bottom of the beaker each time the test was run or if the combustion of the alcohol were to use pure molecular oxygen, as when burnt in pure molecular oxygen that was readily available to be burnt, no soot is created. These improvements would increase the accuracy of the data collected from the
Conversion of Alcohols to Alkyl Halides Lead Author: Mallori Mays Reviewer: Mallori Mays Editor: Mallori Mays Introduction: In this experiment an alcohol was converted to an alkyl halide by both an SN1 and SN2 reactions. Products were obtained by reflux and simple distillation and collected for running spectroscopy data. There are several different Spectroscopy methods used to observe the effects from when light interacts with molecules, depending on the wavelength of light that is used.1 From experiments performed in the past, it is known that UV-VIS uses visible and ultraviolet rays to show any pi bond system with conjugation in the compound, but it is not used for this experiment. IR uses infrared
Introduction of a breathalyser? A breathalyser is a device for estimating blood alcohol content (BAC) from a breath sample. In 1954 Robert F. Borkenstein invented the Breathalyser.
Let me tell you that the majority of automobile accidents in America results from alcohol. The alcohol consumed will be existed in blood and it is known as Blood Alcohol Concentration (BAC). In this condition, someone will experience lowered alertness which can cause someone to loss of judgement and reduce their ability to track moving object. Beside lowered alertness, the muscle control will be lessened causing difficulty steering and less ability to maintain lane position and brake appropriately. People in a state of drunkenness are also hard to detect danger. It may reduce their response to emergency driving situations.
In this experiment, the pKa, dissociation constant, of 2-naphthol was determined by measuring the UV-visible absorption spectra of solution of the acid at different pH values.
An Investigation into the Enthalpies of the Combustion of Alcohols = == == == ==
When the fuels are burnt, energy is given off. I will be calculating the energy given off using the formula above. The specific heat capacity is the energy
The aim of this experiment was to test the heat of combustion over a period of time, and the energy required to combust alcohols with different carbon chain levels. It was hypothesised that the higher the carbon chain of the alcohol present, the faster the heat of combustion will occur. Meaning more energy will be released for a higher carbon chain. After calculating the results from the experiment it was found that the hypothesis was partially supported. The reasoning for this is as the alcohol that posses a higher carbon chain, generally increased there reaction rates. However there were a few exceptions to this rule.
The energy that comes from the combustion from either ethanol or petrol comes from burning these hydrocarbons in order for the oxygen from the air to combine and combust (See Ethanol and the Environment for more). Energy is produced when the hydrocarbon bonds between the carbon and the hydrogen and
The reaction that is involved in burning alcohols is exothermic because heat is given out. From this reason the reactant energy is higher than that of the product.