Concept explainers
(a)
Interpretation:
The type of isomer represented by the pair
Concept Introduction:
Isomers:
The compounds with same molecular formula but differ in the arrangement of the atom are said to be isomers.
Linkage isomers:
Linkage isomerism occurs with ambidentate ligands that are capable of coordinating in more than one way.
Example:
(a)
Answer to Problem 9C.3BST
The type of isomer represented by the pair
Explanation of Solution
In the isomer,
The type of isomer represented by the pair
(b)
Interpretation:
The type of isomer represented by the pair
Concept Introduction:
Hydrate Isomers:
Hydrate isomers results from replacement of a coordinated group by a solvent molecule in this case it is a water molecule.
(b)
Answer to Problem 9C.3BST
The type of isomer represented by the pair
Explanation of Solution
The given pair is
The type of isomer represented by the pair
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Chapter 9 Solutions
Chemical Principles: The Quest for Insight
- Four different octahedral chromium coordination compounds exist that all have the same oxidation state for chromium and have H2O and Cl as the ligands and counterions. When 1 mole of each of the four compounds is dissolved in water, how many moles of silver chloride will precipitate upon addition of excess AgNO3?arrow_forwardDetermine the oxidation state of the coordinated metal atom in each of the following compounds:(a) K[Co(NH3)2(CN)4]; (b) Os(CO)5; (c) Na[Co(OH2)3(OH)3].arrow_forwardName each of the compounds or ions given. (a) [Co(en)2(NO2)Cl]+(b) [Co(en)2Cl2]+(c) [Pt(NH3)2Cl4](d) [Cr(en)3]3+(e) [Pt(NH3)2Cl2]arrow_forward
- Name the compounds (a) [Mo(NH3)3Br3]NO3,(b) (NH4)2[CuBr4]. (c) Write the formula for sodium diaquabis(oxalato)ruthenate(III).arrow_forwardWhich of the following compounds can exhibit cis-trans isomerism? O [Fe(CO)2(NH3)2]?* O [Zn(CO)5Br]* [MNCIBR3]?- O [Cr(CO);NO2]²+ O IFe(H2O)6]³+arrow_forwardDraw all possible molecular structures for the compound with empirical formula [Mn(en)2(NO2)2]. From the structures, identify all pairs that exhibit: (a) geometrical isomerism; (b) linkage isomerism, and (c) optical isomerism.arrow_forward
- Give the proper name for each of the following compounds: (a) Pt(NH3)2Cl2 (b) [Rh(NH3)5Cl]Cl2 (c) [Co(NH3)6](NO3)3 (d) [Co(H2O)4]SO4 (e) [Co(NH3)4(OH2)2](BF4)5 (f) [Fe(H2O)6]Br2 (g) Na3[Fe(CN)6] · 2 H2O (h) Na4[Fe(CN)6] (i) Ni(CO)4 (j) [Cu(NH3)4]SO4 (k) [Pt(en)2](ClO4)2 (l) Co(NH3)2(Cl)(Br)(CH3CO2)arrow_forwardWhich of the following species has a transition metal ion with do electronic configuration? O [Fe(CN)613- O [Mo(NH3)613+ O [COF613- [Co(H2O)6]2+arrow_forward[Co(H2O)6]2+ (aq) + 4 Cl-(aq )⇆ [CoCl4]2-(aq) + 6 H2O 3. Does the value of the equilibrium constant (K) for this reaction increase, decrease, or remain the same as the concentration of chloride increases? Explain your answer incorporating the definition of an equilibrium constant.arrow_forward
- Write the names of [Co(NH3)4CO3] (NO3) and [Cr(NH3)5Cl] Cl2 .arrow_forwardWrite the names of the following compounds. [Ir(NH3)4(H2O)2](NO3) 2 [Cr(NH3)4(CO3)]Clarrow_forwardCompound [Ni(CO)4] [Fe(CN)5] [Cr(OH)6] [Ru(H2O)6]C12 [Co(NH3)6]Br3 [Co(NH3)5Br]Br2 [Co(NH3)6Br2]Br trans [Mn(en)2C12] [Mn(en)(H2O)4] Ca2[VC16] (NH4)2[FeC14] (NH4)3[FeC16] PROBLEM WORKSHEET B [Pd (NH3)4] [Pd(en)2] cis [Pd (NH3)2C12] [Pd(en)2]C12 (NH4)2[Pd(NH3)C13] K3[Co(CN)6] tans [Ir(SO4)2(H2O)4] [Ir(ONO)2(CN)2(CO)2] Coordination number Charge on the metal complex ion Oxidation state Metal d-electron count Structure of metal complex ionarrow_forward
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