Concept explainers
(a)
Interpretation:
Among the given ethers, the one which is most apt to form a peroxide has to be given.
Concept introduction:
Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.
Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.
Peroxide is a radical initiator, it has O-O bond in the molecule.
It is used in the radical reaction for the radical initiator.
(b)
Interpretation:
Among the given ethers, the one which is least apt to form a peroxide has to be given.
Concept introduction:
Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.
Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.
Peroxide is a radical initiator, it has O-O bond in the molecule.
It is used in the radical reaction for the radical initiator.
Want to see the full answer?
Check out a sample textbook solutionChapter 12 Solutions
Organic Chemistry (8th Edition)
- Question one parts A though c a. Which product forms from the following reaction? Answer as letter choice only (i.e., "E" not "E.") CHO HOH HOH H OH H OH CHOH Brs. H0 ??? A. В. C. D. COOH HOH HOH H OH HOH CHOH CH-OH CHO COOH но HO HOH H OH HOH ČOOH HO -H но HO H H OH HOH CHOH HOH H OH COOH b. Which of the following structures shows the Haworth configuration in the alpha configuration of the beginning sugar? Answer as letter choice only (ie. "E" not "E."). сно HO-H HO H Намorth Form Alpha Configuration H- OH нон CHOH B. A. CH,OH CH,OH CH,OH CH,OH OH OH OH O OH OH OP OH он он он OH C. Answer the following question. What is the expected product of this reaction? CHO H- -Он NABH, HO-H H- ??? OH H- -OH ČH,OH 運運重 А. В. С. CH,OH COOH COOH H- HO-H H- OH -OH OH но- но H- H- H OH H- OH OH HHOH H- ČH-OH H- -OH ČH,OH COOHarrow_forwardWhat is the major product of the following reaction? HCI CH:-CH-CH;CH; Select one: O a. CH;-CH-CH;CH;CH; CI O b. CH:-CH-CH,CH; CI Oc. CH: CH-CH;CH; ÓCI O d. no reaction е. CI CH:-C-CH;CH3 CIarrow_forwardSynthesize each compound from benzene.arrow_forward
- 4.arrow_forwardhez 03 ,ace given the general furmula FezO4. Tley yreted elemintal an wken beetall to a reyhghtemacutuce jenth ether cartren mmsael r elemental hydragin. Balane fke ヤarrow_forward5. Draw the products of the following reactions: HBr ether Lindlar catalyst NAOH H2O, heat ...Br H2O H;0 heat CN OH PBrs H3C CH3 ether ČH3 H3C CH, CH3CH2CH2OH water H3C Li CH;CH2 -C=C-CH3 NH3arrow_forward
- organic chemistryarrow_forwardO (1) H20, H*; (2) Jones reagent (1) H20, H*; (2) PCC, CH2CI2 (1) conc. H2SO4: (2) Jones reagent O (1) H20, H*; (2) Tollens reagent (1) conc. H2SO4: (2) PCC, CH2CI2 O (1) conc. H2SO4: (2) Tollens reagentarrow_forward4. Synthesize the following compounds from Bromocyclohexane: A. В. C. D. CNarrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY