Q1:- Arrange the following compounds of each set in order of decreasing acidity ? Explain your choice.butanoic acid,2-bromobutanoic acid,3-bromobutanoic acid,4-bromobutanoic acidQ2:-: Define the following terms? Give examplea- dextrorotatoryb- meso compoundC- specific rotationQ3:- Draw and specify as R or S the enantiomers (if any) of:(a) 3-bromohexane(d) 1,3-dichloropentaneQ4:- Draw structures, give names, and classify as primary, secondary, or tertiary amine :the eight isomeric amines of formula CAH11NQ5:- Give structures and names of the principal organic reactants and products of the following reactions.a- conversion of Carboxylic Acids into Estersb- Hydrolysis of nitrites.c- Hofmann degradation of amidesQ6:- Arrange the compounds of each set in order of basicity ? Explain your choice.ethylamine,2-aminoethanol, 3-amino-l-propanolQ7:- Which compound has the highest boiling point Acetic acid or Propan-1-ol ? Why ?Q8:- How can prepare Acetic acid by Industrial and lab methods ? compere between them ?Q9:- Outline a possible laboratory, synthesis of each of the following compounds from benzene and/ortoluene, using any needed aliphatic and inorganic reagents,(a) m-bromophenol(b) 5-bromo-2-methylphenolQ10:- Explain how Esters are more reactive than amides in nucleophilic acyl substitution reactions.

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Q1:- Arrange the following compounds of each set in order of decreasing acidity ? Explain your choice. butanoic acid, 2-bromobutanoic acid, 3-bromobutanoic acid, 4-bromobutanoic acid Q2:-: Define the following terms? Give example a- dextrorotatory b- meso compound C- specific rotation Q3:- Draw and specify as R or S the enantiomers (if any) of:

Q1:- Arrange the following compounds of each set in order of decreasing acidity ? Explain your choice. butanoic acid, 2-bromobutanoic acid, 3-bromobutanoic acid, 4-bromobutanoic acid Q2:-: Define the following terms? Give example a- dextrorotatory b- meso compound C- specific rotation Q3:- Draw and specify as R or S the enantiomers (if any) of:

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter5: Stereochemistry At Tetrahedral Centers

Section5.SE: Something Extra

Problem 54AP

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