(- )- Mandelic acid has a specific rotation of - 158°. What would be the specific rotation of a solution which contains 50% (- )- mandelic acid and 50% (+ )- mandelic acid? A. 0° B. + 79° C. The value must be experimentally determined D. - 79°
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- Please answer this NEATLY, COMPLETELY, and CORRECTLY for an UPVOTE. Long and detailed explanations are not needed. Keep it short, brief, and direct because I only need the answers as soon as possible. Calculate the % ee of a mixture containing 80% of one enantiomer and 20% of the other? A. 80B. 120C. 60D. 90(+)-Tartaric acid has a specific rotation of +12.0°. Calculate the specific rotation of a mixture of 68% (+)@tartaric acid and 32% (-)@tartaric acid(+) Chloramphenicol is a powerful antibiotic isolated in 1949 from the Streptomyces venezuelae bacterium. Its specific rotation is +18.6°. What is the composition of a mixture of (+) and (-) chloramphenicol whose observed specific rotation is +14.88° ? Select one: A. 60% (+) chloramphenicol and 40 % (-) chloramphenicol B. 70% (+) chloramphenicol and 30 % (-) chloramphenicol C. 90% (+) chloramphenicol and 10 % (-) chloramphenicol D. 80% (+) chloramphenicol and 20 % (-) chloramphenicol
- Saquinavir (trade name Incirase) belongs to a class of drugs called protease inhibitors, which are used to treat HIV. Locate all the stereogenic centers in the drug saquinavir. H. H. N. N. H. NH2 OH O: saquinavir Trade name: Invirase NH O:om/S123187d672a4/74971422X-Blackboard-Expiration=1626199200000&X-Blackboard-Signe to Deliver An E. T Critical Thinking -.. The first time I gave. P What Has Your Exp... 3. Identify the following Flscher projection as the D- or L-Isomer and draw the Flscher prolection of the product when It reacts with Hz In the presence of a catalyst such as platinum. H. но H. HO H OH H. OH CH,OH 4. Draw the condensed structural formulas for the products from the base hydrolysis of the following compound. Heat CH, (CH,), C-O-(CH,),-CH, + NaOH 5. Circle the chiral carbons. NH, CH, CH,-CH-CH=C-CH-CH Br BrThe anti-inflammatory agent, (S)-naproxen sodium salt has a specific rotation of +66°. The commercial preparation of the latter agent results in a mixture that has a 97% enantiomeric excess (ee). Na Hooooja moo (S)-naproxen sodium salt (d) What percentage of each enantiomer is obtained from the above commercial mixture? H3CO (e) Provide a reaction scheme for the formation of the (S)-naproxen sodium salt from "acidic" (S)-naproxen.
- 4. (+)-Tartaric acid has a specific rotation of +12.0°. Calculate the specific rotation of a mixture of 68% (+)-tartaric acid and 32% (-)-tartaric acid. C(+)-Mandelic acid has a specific rotation of +158. What would be the observed specific rotation of each of the following mixtures? a. 50% (-)-mandelic acid and 50% (+)-mandelic acid b. 25% (-)-mandelic acid and 75% (+)-mandelic acid c. 75% (-)-mandelic acid and 25% (+)-mandelic acidGive a clear handwritten answer Draw the 2 chair confirmations of this structure:
- A 1.62 M solution of (R)-2-butanol is mixed with an equal volume of a 0.810 M solution of racemic 2-butanol, and the resulting solution is analyzed in a sample container that is 1 dm long. What observed rotation is expected? The specific rotation of (R)-2-butanol is –13.9 degrees mL g- dm-'. a = degWhat is the appropriate systematic name for the compound below? HO., SH ) (15,45)-4-hydroxycyclohex-2-enethiol O (35,65)-6-mercaptocyclohexen-3-ol )(1S,4S)-4-mercaptocyclohex-2-enol (3S,65)-6-hydroxycyclohexene-3-thiol2. N 3. Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms. a = acceptor d = donor n = no effect 1. CH3 N Inductive effect Resonance effect -NHCH2CH2CH2C=N: Inductive effect Resonance effect :0: -C-OCH2CH2CH3 Inductive effect Resonance effect Submit Answer Retry Entire Group 1 more group attempt remaining