B. A newly isolated natural product was shown to be optically active. If a solution of 2.0 g in 10 mL of ethanol in a 50 cm tube gives a rotation of +2.57°, what is the specific rotation of this natural product?
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- An attempt at synthesizing a certain optically-active compound resulted in a mixture of its enantiomers. The mixture had an observed specific rotation of +14.2°. If it is known that the specific rotation of the R enantiomer is -31.0°, determine the percentage of each isomer in the mixture. R enantiomer: % S enantiomer: %A 0.26 M solution of an enantiomerically pure chiral compound D has an observed rotation of +0.197° in a 1‑dm sample container. The molar mass of the compound is 132.3 g/mol. a. What is the specific rotation of D? b. What is the observed rotation if this solution is mixed with an equal volume of a solution that is 0.26 M in L, the enantiomer of D? c. What is the observed rotation if the solution of D is diluted with an equal volume of solvent?Glutamic acid is a naturally occurring amino acid and isthe precursor to the food additive MSG (monosodium glutamate)which can cause allergic reactions in some people. If naturally occurring L glutamic acid has a melting point of 205 C and an optical rotation of + 31.5, what is the melting point and optical rotation of its enantiomer?
- Glutamic acid is a naturally occurring amino acid and is the precursor to the food additive MSG (monosodium glutamate) which can cause allergic reactions in some people. If naturally occurring L glutamic acid has a melting point of 205 C and an optical rotation of + 31.5, what is the melting point and optical rotation of its enantiomer?The specific rotation, [a]p, for (-)-2-butanol is +14. What is the observed rotation for a solution of 3.3 g of (-)-2-butanol in 10 mL of water in a sample tube having a pathlength of 10 cm? degrees . The observed rotation of a solution of 0.75 g of a compound in 10 mL of water is -6.9 degrees. If the pathlength is 10 cm, what is the specific rotation of the compound?Suppose a solution of a compound gave a rotation of +160o. How could this rotation be distinguihed from one of -200oand from one of +520o?
- The specific rotation, [a]p, for (-)-malic acid is -27. What is the observed rotation for a solution of 0.75 g of (-)-malic acid in 10 mL of water in a sample tube having a pathlength of 10 cm? degrees. The observed rotation of a solution of 1.4 g of a compound in 10 mL of water is +1.3 degrees. If the pathlength is 10 cm, what is the specific rotation of the compound? 9 more group attempts remaining Submit Answer Retry Entire GroupHow can we decide whether an observed rotation of a solution of an optically active compound is +170° and not actually -190°?A solution prepared by mixing 10 mL of a 0.10 M solution of the R enantiomer of a compound and 30 mL of a 0.10 M solution of the S enantiomer was found to have an observed specific rotation of +4.8. What isthe specific rotation of each of the enantiomers? (Hint: mL * M = millimole, abbreviated as mmol)
- The specific rotation of vitamin C ( using the D line of sodium, at 20°C) is +24. Predict what the observed rotation would be for a solution containing 0.100 g of vitamin C dissolved in 10.0 ml of ethanol and placed in a sample cell with a length of 1dm.Use compounds D and E shown below to answer this question. What would be the observed rotation of a 4:1 mixture of D:E if pure compound E has a specific rotation of +12°? Show how you arrived at your answer. (Use the back if necessary) CI, Br Br .CI compound D compound EIf the sample of the pure R enantiomer of a molecule has a specific rotation of -40 degrees and your mixture of that molecule has an 82% ee S, what is the observed specific rotation of your sample?