General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Textbook Question
Chapter 8, Problem 8.47SP
Does a measurement carried out in a bomb calorimeter give a value for ΔH or ΔE? Explain.
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General Chemistry: Atoms First
Ch. 8.2 - Which of the following are state functions, and...Ch. 8.3 - Calculate the work in kilojoules done during a...Ch. 8.3 - How much work is done in kilojoules, and in which...Ch. 8.4 - The following reaction has E = 186 kJ/mol. (a) Is...Ch. 8.5 - Assuming that Coca Cola has the same specific heat...Ch. 8.5 - What is the specific heat of lead if it takes 97.2...Ch. 8.5 - When 25.0 mL of 1.0 M H2SO4 is added to 50.0 mL of...Ch. 8.6 - The reaction between hydrogen and oxygen to yield...Ch. 8.6 - The explosion of 2.00 mol of solid trinitrotoluene...Ch. 8.7 - How much heat in kilojoules is evolved or absorbed...
Ch. 8.7 - Nitromethane (CH3NO2), sometimes used as a fuel in...Ch. 8.8 - The industrial degreasing solvent methylene...Ch. 8.8 - The reaction of A with B to give D proceeds in two...Ch. 8.8 - Draw a Hesss law diagram similar to that in...Ch. 8.9 - Use the information in Table 8.2 to calculate H in...Ch. 8.9 - Use the information in Table 8.2 to calculate H in...Ch. 8.10 - Use the data in Table 8.3 to calculate an...Ch. 8.10 - Use the data in Table 8.3 to calculate an...Ch. 8.11 - Liquid butane (C4H10), the fuel used in many...Ch. 8.12 - Ethane, C2H6, can be prepared by the reaction of...Ch. 8.12 - Is the reaction represented in the following...Ch. 8.12 - Which of the following reactions are spontaneous...Ch. 8.12 - Is the Haber process for the industrial synthesis...Ch. 8.12 - The following reaction is exothermic: (a) Write a...Ch. 8.12 - Write balanced equations for the combustion...Ch. 8.12 - Biodiesel has a more favorable (more negative)...Ch. 8 - The following reaction is exothermic: (a) Write a...Ch. 8 - Imagine a reaction that results in a change in...Ch. 8 - Redraw the following diagram to represent the...Ch. 8 - Prob. 8.30CPCh. 8 - Prob. 8.31CPCh. 8 - A reaction is carried out in a cylinder fitted...Ch. 8 - The following drawing portrays a reaction of the...Ch. 8 - Prob. 8.34CPCh. 8 - The following reaction of A3 molecules is...Ch. 8 - Prob. 8.36SPCh. 8 - What is internal energy?Ch. 8 - Prob. 8.38SPCh. 8 - Assume that the kinetic energy of a 1400 kg car...Ch. 8 - Prob. 8.40SPCh. 8 - The addition of H2 to CC double bonds is an...Ch. 8 - Prob. 8.42SPCh. 8 - Prob. 8.43SPCh. 8 - Prob. 8.44SPCh. 8 - Prob. 8.45SPCh. 8 - Prob. 8.46SPCh. 8 - Does a measurement carried out in a bomb...Ch. 8 - Prob. 8.48SPCh. 8 - Prob. 8.49SPCh. 8 - Prob. 8.50SPCh. 8 - When 0.187 g of benzene, C6H6, is burned in a bomb...Ch. 8 - When a solution containing 8.00 g of NaOH in 50.0...Ch. 8 - Prob. 8.53SPCh. 8 - Prob. 8.54SPCh. 8 - Prob. 8.55SPCh. 8 - Prob. 8.56SPCh. 8 - Prob. 8.57SPCh. 8 - Prob. 8.58SPCh. 8 - Prob. 8.59SPCh. 8 - Prob. 8.60SPCh. 8 - Prob. 8.61SPCh. 8 - Used in welding metals, the reaction of acetylene...Ch. 8 - Prob. 8.63SPCh. 8 - The familiar ether used as an anesthetic agent is...Ch. 8 - How much energy in kilojoules is required to...Ch. 8 - Prob. 8.66SPCh. 8 - Prob. 8.67SPCh. 8 - Prob. 8.68SPCh. 8 - Prob. 8.69SPCh. 8 - Prob. 8.70SPCh. 8 - Prob. 8.71SPCh. 8 - Prob. 8.72SPCh. 8 - Prob. 8.73SPCh. 8 - Prob. 8.74SPCh. 8 - Prob. 8.75SPCh. 8 - Prob. 8.76SPCh. 8 - Prob. 8.77SPCh. 8 - Prob. 8.78SPCh. 8 - Prob. 8.79SPCh. 8 - Prob. 8.80SPCh. 8 - Prob. 8.81SPCh. 8 - Styrene (C8H8), the precursor of polystyrene...Ch. 8 - Prob. 8.83SPCh. 8 - Prob. 8.84SPCh. 8 - Prob. 8.85SPCh. 8 - Prob. 8.86SPCh. 8 - Prob. 8.87SPCh. 8 - Use the bond dissociation energies in Table 8.3 on...Ch. 8 - Use the bond dissociation energies in Table 8.3 to...Ch. 8 - Prob. 8.90SPCh. 8 - Prob. 8.91SPCh. 8 - Prob. 8.92SPCh. 8 - Prob. 8.93SPCh. 8 - Prob. 8.94SPCh. 8 - Prob. 8.95SPCh. 8 - Prob. 8.96SPCh. 8 - Prob. 8.97SPCh. 8 - Prob. 8.98SPCh. 8 - Prob. 8.99SPCh. 8 - Prob. 8.100SPCh. 8 - Prob. 8.101SPCh. 8 - Prob. 8.102SPCh. 8 - Tell whether reactions with the following values...Ch. 8 - Prob. 8.104SPCh. 8 - Prob. 8.105SPCh. 8 - Prob. 8.106SPCh. 8 - Prob. 8.107SPCh. 8 - Prob. 8.108SPCh. 8 - Prob. 8.109SPCh. 8 - When 1.50 g of magnesium metal is allowed to react...Ch. 8 - Use the data in Appendix B to find standard...Ch. 8 - Prob. 8.112CHPCh. 8 - The boiling point of a substance is defined as the...Ch. 8 - What is the melting point of benzene in kelvin if...Ch. 8 - Metallic mercury is obtained by heating the...Ch. 8 - Prob. 8.116CHPCh. 8 - Methanol (CH3OH) is made industrially in two steps...Ch. 8 - Isooctane, C8H18, is the component of gasoline...Ch. 8 - We said in Section 8.1 that the potential energy...Ch. 8 - For a process to be spontaneous, the total entropy...Ch. 8 - Set up a Hesss law cycle, and use the following...Ch. 8 - Prob. 8.122CHPCh. 8 - Prob. 8.123CHPCh. 8 - Prob. 8.124CHPCh. 8 - Citric acid has three dissociable hydrogens. When...Ch. 8 - Prob. 8.126CHPCh. 8 - Imagine that you dissolve 10.0 g of a mixture of...Ch. 8 - Prob. 8.128CHPCh. 8 - Prob. 8.129MPCh. 8 - Phosgene, COCl2(g), is a toxic gas used as an...Ch. 8 - Prob. 8.131MPCh. 8 - (a) Write a balanced equation for the reaction of...Ch. 8 - Prob. 8.133MPCh. 8 - Reaction of gaseous fluorine with compound X...
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- Coal is used as a fuel in some electric-generating plants. Coal is a complex material, but for simplicity we may consider it to be a form of carbon. The energy that can be derived from a fuel is sometimes compared with the enthalpy of the combustion reaction: C(s)+O2(g)CO2(g) Calculate the standard enthalpy change for this reaction at 25C. Actually, only a fraction of the heat from this reaction is available to produce electric energy. In electric generating plants, this reaction is used to generate heat for a steam engine, which turns the generator. Basically the steam engine is a type of heat engine in which steam enters the engine at high temperature (Th), work is done, and the steam then exits at a lower temperature (Tl). The maximum fraction, f, of heat available to produce useful energy depends on the difference between these temperatures (expressed in kelvins), f = (Th Tl)/Th. What is the maximum heat energy available for useful work from the combustion of 1.00 mol of C(s) to CO2(g)? (Assume the value of H calculated at 25C for the heat obtained in the generator.) It is possible to consider more efficient ways to obtain useful energy from a fuel. For example, methane can be burned in a fuel cell to generate electricity directly. The maximum useful energy obtained in these cases is the maximum work, which equals the free-energy change. Calculate the standard free-energy change for the combustion of 1.00 mol of C(s) to CO2(g). Compare this value with the maximum obtained with the heat engine described here.arrow_forwardAt 298 K, the standard enthalpies of formation for C2H2(g) and C6H6(l) are 227 kJ/mol and 49 kJ/mol, respectively. a. Calculate H for C6H6(l)3C2H2(g) b. Both acetylene (C2H2) and benzene (C6H6) can be used as fuels. Which compound would liberate more energy per gram when combusted in air?arrow_forwardThe formation of aluminum oxide from its elements is highly exothermic. If 2.70 g Al metal is burned in pure O2 to give A12O3, calculate how much thermal energy is evolved in the process (at constant pressure).arrow_forward
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