EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Question
Chapter 7, Problem 90ASP
Interpretation Introduction
Interpretation :
It is required to choose which of the provided processes is not a logical retrosynthesis.
Concept Introduction :
A Retrosynthetic analysis helps to disconnect bonds to get suitable starting materials for the synthesis of target molecule.
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In this lab you are performing your first organic synthesis and safety information on all the materials you are using must be obtained.
Companies are required to provide material safety data sheets (MSDS) for chemical compounds they sell.
Please examine the MSDS for acetic anhydride, available here. You will find GHS pictograms within the sheet that summarize the
main hazards of this compound. The pictograms are essentially the same as the symbols on WHMIS labels, available here for
reference.
Based on the pictograms, whatare the main hazards for acetic anhydride? Select as many answers as appropriate
Select one or more:
Carcinogen
Gas under pressure
Acute oral or inhalation toxicity
Corrosive
Flammable material
Oxidizing material
Self-reactive substance
In this lab you are performing your first organic synthesis and safety information on all the materials you
are using must be obtained.
Companies are required to provide material safety data sheets (MSDS) for chemical compounds they
sell.
Please examine the MSDS for acetic anhydride, available here. You will find GHS pictograms within the
sheet that summarize the main hazards of this compound. The pictograms are essentially the same as
the symbols on WHMIS labels, available here for reference.
Based on the pictograms, whatare the main hazards for acetic anhydride? Select as many answers as
appropriate however points will be deducted for incorrect guesses.
Select one or more:
Corrosive
Flammable material
Acute oral or inhalation toxicity
Oxidizing material
Carcinogen
Self-reactive substance
Gas under pressure
20:32
hydroxide
2. Using curved arrows, show the deprotonation mechanism of phenol with
(OH). Also, provide the structure of the product of this deprotonation.
Start answering this question by drawing the structure of phenol. Then
hydroxide ion. Find your most reactive electrons and draw the curved arrow that
shows where they would go to deprotonate phenol. Then "make a bond break a
bond"
write they
question
3. Provide valid resonance structures for the product of
the previous
arrow(s)
charge moving onto the ortho- and para positions. Use curved
to show how the charge resonates to the next structure in your scheme.
all the proper notations for depicting resonance.
that show the
in the structures
Be sure to use
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Chapter 7 Solutions
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
Ch. 7.2 - Prob. 1CCCh. 7.3 - Prob. 2CCCh. 7.3 - Prob. 1LTSCh. 7.3 - Prob. 3PTSCh. 7.3 - Prob. 4ATSCh. 7.3 - Prob. 2LTSCh. 7.3 - Prob. 5PTSCh. 7.3 - Prob. 6ATSCh. 7.3 - Prob. 7CCCh. 7.4 - Prob. 8CC
Ch. 7.5 - Prob. 9CCCh. 7.6 - Prob. 10CCCh. 7.6 - Prob. 11CCCh. 7.7 - Prob. 12PTSCh. 7.7 - Prob. 13PTSCh. 7.7 - Prob. 14ATSCh. 7.7 - Prob. 4LTSCh. 7.7 - Prob. 16ATSCh. 7.7 - Prob. 17CCCh. 7.7 - Prob. 18CCCh. 7.7 - Prob. 5LTSCh. 7.7 - Prob. 19PTSCh. 7.7 - Prob. 20ATSCh. 7.8 - Prob. 21PTSCh. 7.8 - Prob. 22ATSCh. 7.8 - Prob. 23CCCh. 7.8 - Prob. 24CCCh. 7.8 - Prob. 25CCCh. 7.8 - Prob. 26CCCh. 7.8 - Prob. 27CCCh. 7.9 - Prob. 7LTSCh. 7.9 - Prob. 29ATSCh. 7.9 - Prob. 30ATSCh. 7.9 - Prob. 31ATSCh. 7.10 - Prob. 32CCCh. 7.10 - Prob. 33CCCh. 7.10 - Prob. 34CCCh. 7.11 - Prob. 8LTSCh. 7.11 - Prob. 35PTSCh. 7.11 - Prob. 36PTSCh. 7.11 - Prob. 37ATSCh. 7.11 - Prob. 9LTSCh. 7.11 - Prob. 40PTSCh. 7.11 - Prob. 41ATSCh. 7.12 - Prob. 42CCCh. 7.12 - Prob. 43CCCh. 7.12 - Prob. 44CCCh. 7.12 - Prob. 45CCCh. 7.12 - Prob. 46CCCh. 7 - Prob. 47PPCh. 7 - Prob. 48PPCh. 7 - Prob. 49PPCh. 7 - Prob. 50PPCh. 7 - Prob. 51PPCh. 7 - Prob. 52PPCh. 7 - Prob. 53PPCh. 7 - Prob. 54PPCh. 7 - Prob. 55PPCh. 7 - Prob. 56PPCh. 7 - Prob. 57PPCh. 7 - Prob. 58PPCh. 7 - Prob. 59PPCh. 7 - Prob. 60PPCh. 7 - Prob. 61PPCh. 7 - Prob. 64PPCh. 7 - Indicate whether you would use NaOEt or tBuOK to...Ch. 7 - Prob. 68PPCh. 7 - Draw a plausible mechanism for each of the...Ch. 7 - Prob. 70PPCh. 7 - Prob. 71PPCh. 7 - Prob. 72PPCh. 7 - Prob. 73PPCh. 7 - Prob. 74PPCh. 7 - Prob. 77PPCh. 7 - Prob. 78PPCh. 7 - Prob. 81ASPCh. 7 - Prob. 87ASPCh. 7 - Prob. 90ASPCh. 7 - Prob. 91IPCh. 7 - Prob. 92IPCh. 7 - Prob. 93IPCh. 7 - Prob. 94IPCh. 7 - Prob. 95IPCh. 7 - Prob. 96IPCh. 7 - Prob. 97IPCh. 7 - Prob. 98IPCh. 7 - Prob. 99IPCh. 7 - Prob. 100IPCh. 7 - Prob. 101IPCh. 7 - Prob. 102IPCh. 7 - Prob. 103IPCh. 7 - Prob. 105IPCh. 7 - Prob. 106IPCh. 7 - Prob. 107IPCh. 7 - Prob. 109IPCh. 7 - Prob. 110CPCh. 7 - Prob. 112CPCh. 7 - Prob. 114CP
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