(a) Interpretation: The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified. Concept introduction: An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

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Answer 1

Question

Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

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Draw each molecule given its name and the followinginformation. (a) Nitroglycerin, also known as 1,2,3-trinitroxypropane, the active ingredient in dynamiteand a medication administered to people having a heartattack, (Hint: The nitroxy group is the conjugate base ofnitric acid.) (b) Putrescine, also known as 1,4-diaminobutane,the compound responsible for the odor of putrefyingfish, (c) Cyclohexanone, the precursor to Nylon,(d) 1,1,2,2-tetrafluoroethene, the precursor to Teflon,(e) Oleic acid, also known as cis-9-octanedecenoic acid, amonounsaturated fatty acid found in many fats and oils.Draw the correct isomer.

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Answer 2

Question

Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

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Answer 3

Question

Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

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Answer 4

Question

Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

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Answer 5

Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 6

Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 7

Chapter 6, Problem 6.40AP

Interpretation Introduction

(a)

Interpretation:

The compounds out of given compounds that can in principle be resolved into enantiomers are to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The asymmetric center in omeprazole is to be identified.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The S enantiomer of omeprazole is to be drawn.

Concept introduction:

An atom that has four nonequivalent atoms or groups attached to it is known as the chiral atom. Chiral centers are also called asymmetric or stereogenic centers. An atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral atom.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 6 - Prob. 6.1P Ch. 6 - Prob. 6.2P Ch. 6 - Prob. 6.3P Ch. 6 - Prob. 6.4P Ch. 6 - Prob. 6.5P Ch. 6 - Prob. 6.6P Ch. 6 - Prob. 6.7P Ch. 6 - Prob. 6.8P Ch. 6 - Prob. 6.9P Ch. 6 - Prob. 6.10P

Solution Summary: The author explains that asymmetric centers in omeprazole can be resolved into enantiomers.

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