Concept explainers
The reaction of an element
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Introductory Chemistry: A Foundation
- The present average concentration (mass percent) of magnesium ions in seawater is 0.13%. A chemistry textbook estimates that if 1.00 × 108 tons Mg were taken out of the sea each year, it would take one million years for the Mg concentration to drop to 0.12%. Do sufficient calculations to either verify or refute this statement. Assume that Earth is a sphere with a diameter of 8000 mi, 67% of which is covered by oceans to a depth of 1 mi, and that no Mg is washed back into the oceans at any time.arrow_forwardThe reusable booster rockets of the space shuttle use a mixture of aluminum and ammonium perchlorate as fuel. A possible reaction is 3Al(s)+3NH4ClO4(s)Al2O3(s)+AlCl3(s)+3NO(g)+6H2O(g) Calculate H for this reactionarrow_forwardSilicon is produced for the chemical and electronics industries by the following reactions. Give the balanced equation for each reaction. a. SiO2(s)+C(s)arefurnaceElectricSi(s)+CO(g) b. Liquid silicon tetrachloride is reacted with very pure solid magnesium, producing solid silicon and solid magnesium chloride. c. Na2SiF6(s) + Na(s) Si(s) + NaF(s)arrow_forward
- How is the addition of heat symbolized in a chemical equation? The addition of light energy?arrow_forwardThe carbon dioxide exhaled in the breath of astronauts is often removed from the spacecraft by reaction with lithium hydroxide 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) Estimate the grams of lithium hydroxide required per astronaut per day. Assume that each astronaut requires 2.50 103 kcal of energy per day. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 2.50 103 kcal of heat, calculate the amount of CO2 produced and hence the amount of LiOH required. The H for glucose(s) is 1273 kJ/mol.arrow_forward4.64 Using the web, find information about the amount of lead in the environment during the past 50 years. Correlate what you observe with the presence or absence of tetraethyl lead in gasoline.arrow_forward
- Ethanol, C2H5OH, is a gasoline additive that can be produced by fermentation of glucose. C6H12O62C2H5OH+2CO2 (a) Calculate the mass (g) of ethanol produced by the fermentation of 1.000 lb glucose. (b) Gasohol is a mixture of 10.00 mL ethanol per 90.00 mL gasoline. Calculate the mass (in g) of glucose required to produce the ethanol in 1.00 gal gasohol. Density of ethanol = 0.785 g/mL. (c) By 2022, the U. S. Energy Independence and Security Act calls for annual production of 3.6 1010 gal of ethanol, no more than 40% of it produced by fermentation of corn. Fermentation of 1 ton (2.2 103 lb) of corn yields approximately 106 gal of ethanol. The average corn yield in the United States is about 2.1 105 lb per 1.0 105 m2. Calculate the acreage (in m2) required to raise corn solely for ethanol production in 2022 in the United States.arrow_forward4-102 Aspartame, an artificial sweetener used as a sugar substitute in some foods and beverages, has the molecular formula C14H18N2O5. (a) How many mg of aspartame are present in 3.72 × 1026 molecules of aspartame? (b) Imagine you obtain 25.0 mL of aspartame, which is known to have a density of 1.35 g/mL. How many molecules of aspartame are present in this volume? (c) How many hydrogen atoms are present in 1.00 mg of aspartame? (d) Complete the skeletal structure of aspartame, where all the bonded atoms are shown but double bonds, triple bonds, and/or lone pairs are missing. (e) Identify the various types of geometries present in each central atom of aspartame using VSEPR theory. (f) Determine the various relative bond angles associated with each central atom of aspartame using VSEPR theory. (g) What is the most polar bond in aspartame? (h) Would you predict aspartame to be polar or nonpolar? (i) Is aspartame expected to possess resonance? Explain why or why not. (j) Consider the combustion of aspartame, which results in formation of NO2(g) as well as other expected products. Write a balanced chemical equation for this reaction. (k) Calculate the weight of C02(g) that can be prepared from 1.62 g of aspartame mixed with 2.11 g of oxygen gas.arrow_forward
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