General Chemistry: Atoms First
General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 3, Problem 3.90SP
Interpretation Introduction

Interpretation:

The Born-Haber cycle for formation of sodium hydridehas to be drawn.

Concept introduction:

Born-Haber cycle:

Born-Haber cycle determines the energy of a reaction. It deals with reactions between metals and halogen or non-metals leads to form ionic compounds. There are few steps to form a ionic compound and it is mentioned below

  1. 1. Electron affinity(EA)
  2. 2.  Ionization energy(IE)
  3. 3. Sublimation energy (ΔHsub)
  4. 4. Bond dissociation energy (ΔHdiss)
  5. 5. Lattice energy(U)
  6. 6. Net energy (ΔHf0)

ΔHf0=ΔHsub+IE+ΔHdiss+EA+U

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Students have asked these similar questions
Use the following data and the Born-Haber cycle to calculate the first ionization energy (ΔH IE1) of K(g) K(s) → K(g) 89 kJ mol-1 Cl(g) + e– → Cl–(g) -349 kJ mol-1 K(s) + ½ Cl2(g) → KCl(s) -437 kJ mol-1 K(g) → K+(g) + e– ΔH IE1 Cl2(g) → 2Cl(g) 244 kJ mol-1 K+(g) + Cl–(g) → KCl(s) -717 kJ mol-1
Use the following data and the Born-Haber cycle to calculate the first ionization energy (ΔH IE1) of K(g) K(s) → K(g) 89 kJ mol-1 Cl(g) + e– → Cl–(g) -349 kJ mol-1 K(s) + ½ Cl2(g) → KCl(s) -437 kJ mol-1 K(g) → K+(g) + e– ΔH IE1 Cl2(g) → 2Cl(g) 244 kJ mol-1 K+(g) + Cl–(g) → KCl(s) -717 kJ mol-1 Use the bond energies listed in the table below to estimate the standard enthalpy of the reaction: CCl3CHCl2(g) + 2HF(g) → CCl3CHF2(g) + 2HCl(g) C – H 412 kJ mol-1 C – C 348 kJ mol-1 C – Cl 338 kJ mol-1 H – Cl 431 kJ mol-1 C – F 484 kJ mol-1 H – F 565 kJ mol-1
Given: Enthalpy of atomisation of calcium =+ 178 kJ First ionisation energy of calcium =+590 kJ Second ionisation energy of calcium = +1145 kJ Enthalpy of atomisation of chlorine =+ 121 kJ Electron affinity of chlorine Lattice energy of calcium chloride =- 2258 kJ = - 346 kJ Construct a Born-Haber cycle for calcium chloride, CaCl2 by using the data given above. Hence, calculate the enthalpy of formation of calcium chloride. b. The enthalpy of solution for calcium chloride crystal is -81.3 kJ mol'. Based on the data from the above Born-Haber cycle, calculate the enthalpy change for the reaction below: Ca" (g) + 2CI (g)–→ Ca* (aq) + 2CI¯ (aq)

Chapter 3 Solutions

General Chemistry: Atoms First

Ch. 3.4 - Prob. 3.11PCh. 3.4 - which of the following spheres represents a K+...Ch. 3.5 - Using the periodic table as your guide, predict...Ch. 3.6 - (a) Which has the larger third ionization energy,...Ch. 3.6 - Three atoms have the following electron...Ch. 3.6 - Order the indicated three elements according to...Ch. 3.7 - Prob. 3.17PCh. 3.7 - Which of the indicated three elements has the...Ch. 3.8 - What noble-gas configurations are the following...Ch. 3.8 - Prob. 3.20PCh. 3.9 - Calculate the net energy change in kilojoules per...Ch. 3.10 - Which substance in each of the following pairs has...Ch. 3.10 - One of the following pictures represents NaCl and...Ch. 3.11 - Prob. 3.24PCh. 3.11 - Complete the following equations so that the same...Ch. 3.12 - Prob. 3.26PCh. 3.12 - Prob. 3.27PCh. 3.14 - Prob. 3.28PCh. 3 - In the following drawings, red spheres represent...Ch. 3 - Which of the following drawings is more likely to...Ch. 3 - Prob. 3.31CPCh. 3 - Prob. 3.32CPCh. 3 - Prob. 3.33CPCh. 3 - Prob. 3.34CPCh. 3 - Prob. 3.35CPCh. 3 - Prob. 3.36CPCh. 3 - Prob. 3.37CPCh. 3 - Prob. 3.38SPCh. 3 - Prob. 3.39SPCh. 3 - Prob. 3.40SPCh. 3 - Prob. 3.41SPCh. 3 - Prob. 3.42SPCh. 3 - Prob. 3.43SPCh. 3 - Prob. 3.44SPCh. 3 - Prob. 3.45SPCh. 3 - Prob. 3.46SPCh. 3 - Prob. 3.47SPCh. 3 - Prob. 3.48SPCh. 3 - Prob. 3.49SPCh. 3 - Prob. 3.50SPCh. 3 - Prob. 3.51SPCh. 3 - Prob. 3.52SPCh. 3 - What is the identity of the element X in the...Ch. 3 - Prob. 3.54SPCh. 3 - Prob. 3.55SPCh. 3 - Prob. 3.56SPCh. 3 - Prob. 3.57SPCh. 3 - Prob. 3.58SPCh. 3 - Prob. 3.59SPCh. 3 - Prob. 3.60SPCh. 3 - Prob. 3.61SPCh. 3 - Prob. 3.62SPCh. 3 - Prob. 3.63SPCh. 3 - Prob. 3.64SPCh. 3 - Prob. 3.65SPCh. 3 - Prob. 3.66SPCh. 3 - Prob. 3.67SPCh. 3 - Which element in each of the following sets has...Ch. 3 - Prob. 3.69SPCh. 3 - Prob. 3.70SPCh. 3 - Prob. 3.71SPCh. 3 - Prob. 3.72SPCh. 3 - Prob. 3.73SPCh. 3 - Prob. 3.74SPCh. 3 - Prob. 3.75SPCh. 3 - Prob. 3.76SPCh. 3 - Prob. 3.77SPCh. 3 - Prob. 3.78SPCh. 3 - Order the following compounds according to their...Ch. 3 - Calculate the energy change in kilojoules per mole...Ch. 3 - Prob. 3.81SPCh. 3 - Prob. 3.82SPCh. 3 - Prob. 3.83SPCh. 3 - Prob. 3.84SPCh. 3 - Prob. 3.85SPCh. 3 - Calculate the overall energy change in kilojoules...Ch. 3 - The estimated lattice energy for CsF2(s) is +2347...Ch. 3 - Prob. 3.88SPCh. 3 - Prob. 3.89SPCh. 3 - Prob. 3.90SPCh. 3 - Prob. 3.91SPCh. 3 - Prob. 3.92SPCh. 3 - Prob. 3.93SPCh. 3 - Prob. 3.94SPCh. 3 - Prob. 3.95SPCh. 3 - Prob. 3.96SPCh. 3 - Prob. 3.97SPCh. 3 - Prob. 3.98SPCh. 3 - Prob. 3.99SPCh. 3 - Prob. 3.100CHPCh. 3 - Prob. 3.101CHPCh. 3 - Prob. 3.102CHPCh. 3 - Prob. 3.103CHPCh. 3 - Prob. 3.104CHPCh. 3 - Prob. 3.105CHPCh. 3 - Prob. 3.106CHPCh. 3 - Prob. 3.107CHPCh. 3 - Prob. 3.108CHPCh. 3 - Prob. 3.109CHPCh. 3 - Prob. 3.110CHPCh. 3 - Prob. 3.111CHPCh. 3 - Prob. 3.112CHPCh. 3 - Prob. 3.113CHPCh. 3 - Prob. 3.114CHPCh. 3 - Given the following information, construct a...Ch. 3 - Given the following information, construct a...Ch. 3 - Consider the electronic structure of the element...Ch. 3 - Prob. 3.118MPCh. 3 - Prob. 3.119MP
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