Organic Chemistry (9th Edition)
Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Chapter 25.4, Problem 25.5P

Several commercial laundry soaps contain water-softening agents, usually sodium carbonate (Na2CO3) or sodium phosphate (Na3PO4 or Na2HPO4). Explain how these water-softening agents allow soaps to be used in water that is hard by virtue of its

  1. a. low pH.
  2. b. dissolved Ca2+, Mg2+, and Fe3+ salts.
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16. Propanoic acid, CH3CH2COOH together with its sodium salt, CH3CH2COONA is used as preservatives in the food industry. a. Write an equation for the dissociation of the acid in water. b. Calculate its acid dissociation constant if the pH of 0.24 M of the acid is 2.75. c. Write an equation for the hydrolysis of the sodium salt, CH3CH2COONA in water. Calculate the hydrolysis constant of the salt.
Use Table 1 to determine if the following equilibria will move left or right i. HF (aq) + NH3 (aq) = F¯ (aq) + NH4 + (aq) ii. HCO3¯ (aq) + SO4²- (aq) =CO3²- (aq) + HSO4 (aq) table 1. Relative strengths for some conjugate acid-base pairs: ACID BASE 100% ionized in H₂O Acid strength increases Strong Weak HCI CIT H₂SO4 HSO4 HNO3 NO3 H3O+ (aq) H₂O HSO4 SO₂²- H3PO4 H₂PO4 HF F™ HC₂H30₂ C₂H₂O₂ H₂CO3 HCO3 HS H₂S H₂PO4 HPO4²- NH4+ NH3 HCO3 HPO ²- CO3²- PO4³- H₂O OH™ OH 0²- H₂ H™ CH4 CH3 Negligible Base strength increases Weak Strong 100% protonated in H₂O
What is the pH of a solution containing a mixture of 0.050 M HC2H3O2 and 0.025 M NaC2H3O2?  (Ka = 1.8 × 10-5 for HC2H3O2)   a. 4.74   b. 4.44   c. 2.87   d. 5.05
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