Concept explainers
(a)
Interpretation:
The product that is formed when the given alcohol is oxidized by dilute
Concept introduction:
Oxidation is a type of reaction in which addition of oxygen atom or removal of hydrogen atom takes place. It occurs by loss of electrons. The substance which gets reduced in a reaction is called the oxidizing agent. Oxidizing agent is the substance that causes oxidation in
(b)
Interpretation:
The product that is formed when the alcohol,
Concept introduction:
Oxidation is a type of reaction in which addition of oxygen atom or removal of hydrogen atom takes place. It occurs by loss of electrons. The substance which gets reduced in a reaction is called the oxidizing agent. Oxidizing agent is the substance that causes oxidation in redox reaction. The carbonyls get oxidized to give carboxylic acids. The alcohols convert into carbonyls or carboxylic acids which depend on the effect of the oxidizing agents.
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Organic Chemistry
- For each molecular formula, draw all the possible constitutional isomers of alcohols withthat formula. Give the IUPAC name for each alcohol.(a) C3H8O (b) C4H10O (c) C3H6O (d) C3H4Oarrow_forwardGive an IUPAC and common name for each of the following naturally occurring carboxylic acids: (a) CH3CH(OH)CO2H (lactic acid); (b) HOCH2CH2C(OH)(CH3)CH2CO2H (mevalonic acid).arrow_forwardGive a systematic (IUPAC) name for each diol.(a) CH3CH(OH)(CH2)4CH(OH)C(CH3)3arrow_forward
- What is the chemical equation when nitrating mixture is added to the following:(a) Cyclohexane (b) Cyclohexene(c) Toluenearrow_forwardUse the symbol (V) to indicate a positive reaction and the symbol (X) to indicate a negative reaction and a () if a test was not performed in the shaded columns. Don't forget to write the number of your unknown underneath where it says number! IDENTIFICATION OF A CARBONYL COMPOUND (GROUP I) Unknowns Number Number methyl ketone Test Aldehyde ketone DNP Fehling's Tollen's X lodoform X Therefore, unknown number is IDENTIFICATION OF ALCOHOL (GROUP II) Unknown Primary alcohol Secondary Tertiary alcohol number: alcohol Test Lucas (in ~5 mins) (immediately) Bordwell - Wellman Therefore, unknown number is > x x >arrow_forwardFor each molecular formula, draw all the possible constitutional isomers of alcohols withthat formula. Give the IUPAC name for each alcohol.(a) C3H8Oarrow_forward
- Which of the isomeric C4H₁0O alcohols can be prepared by hydrogenation of aldehydes? Which can be prepared by hydrogenation of ketones? Which cannot be prepared by hydrogenation of a carbonyl compound?arrow_forwardGive both the IUPAC name and the common name for each alcohol.(a) CH3CH2CH(OH)CH3arrow_forwardDraw and name all phenols with the formula C7H8O.arrow_forward
- Describe how would you distinguish the following pairs, (a) Benzene and cyclohexane (b) Phenol and toluene (c) Phenol and benzoic acid (d) methanol and isopropyl alcoholarrow_forwardWhen the conjugate acid of aniline, C6H5NH3+, reacts with the acetate ion, the following reaction takes place: C6H5NH3+(aq)+CH3COO(aq)C6H5NH2(aq)+CH3COOH(aq) If Kafor C6H5NH3+ is 1.35105 and Kafor CH3COOH is 1.86105 , what is K for the reaction?arrow_forwardCompound A and compound B are different alcohols with the same molecular formula of C4H10O. When reacted with chromic acid (H2CrO4), compound A and compound B produce compound C and compound D, respectively. Compound C has a molecular formula of C4H8O2. Compound E is obtained when compound A reacts with pyridinium chlorochromate (PCC) in a solvent such as dichloromethane (CH2Cl2). Draw the structure of compound A, B, C, D and E.arrow_forward
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning