Which compound among a) acetone b) acetophenone c) propanal d) acetic acid e) acetonitrile will undergo haloform reaction is to be stated. Concept introduction: Methyl ketones when treated with excess halogens in the presence of aqueous bases undergo haloform reaction. The methyl ketone is triply halogenated and the cleaved by the base to yield the salt of a carboxylic acid and a haloform. To state: Which compound among acetone, acetophenone, propanal, acetic acid, acetonitrile will give haloform reaction.

Question

The enamine prepared from acetone and dimethylamine is shown here in its lowest-energy form. (a) What is the geometry and hybridization of the nitrogen atom? (b) What orbital on nitrogen holds the lone pair of electrons? (c) What is the geometric relationship between the p orbitals of the double bond and the nitrogen orbital that holds the lone pair? Why do you think this geometry represents the minimum energy?

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 22.SE, Problem 47AP

Interpretation Introduction

Interpretation:

Which compound among a) acetone b) acetophenone c) propanal d) acetic acid e) acetonitrile will undergo haloform reaction is to be stated.

Concept introduction:

Methyl ketones when treated with excess halogens in the presence of aqueous bases undergo haloform reaction. The methyl ketone is triply halogenated and the cleaved by the base to yield the salt of a carboxylic acid and a haloform.

To state:

Which compound among acetone, acetophenone, propanal, acetic acid, acetonitrile will give haloform reaction.

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The enamine prepared from acetone and dimethylamine is shown here in its lowest-energy form. (a) What is the geometry and hybridization of the nitrogen atom? (b) What orbital on nitrogen holds the lone pair of electrons? (c) What is the geometric relationship between the p orbitals of the double bond and the nitrogen orbital that holds the lone pair? Why do you think this geometry represents the minimum energy?

2) Identify whether each of the following reaction performs a SN1, SN2, E1 or E2; Then, draw the appropriate products. Meo (a) NH2 (d) Br Br он (b) (e) ELOH HO Br (c) (f) Br

Which of the following substances would undergo the haloform reaction? Explain. (c) CHỊCH,CHO (a) CH3COCH3 (d) CH3CO₂H (b) Acetophenone (e) CH3C=N

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 22.SE, Problem 47AP

Interpretation Introduction

Interpretation:

Which compound among a) acetone b) acetophenone c) propanal d) acetic acid e) acetonitrile will undergo haloform reaction is to be stated.

Concept introduction:

Methyl ketones when treated with excess halogens in the presence of aqueous bases undergo haloform reaction. The methyl ketone is triply halogenated and the cleaved by the base to yield the salt of a carboxylic acid and a haloform.

To state:

Which compound among acetone, acetophenone, propanal, acetic acid, acetonitrile will give haloform reaction.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 22.SE, Problem 47AP

Interpretation Introduction

Interpretation:

Which compound among a) acetone b) acetophenone c) propanal d) acetic acid e) acetonitrile will undergo haloform reaction is to be stated.

Concept introduction:

Methyl ketones when treated with excess halogens in the presence of aqueous bases undergo haloform reaction. The methyl ketone is triply halogenated and the cleaved by the base to yield the salt of a carboxylic acid and a haloform.

To state:

Which compound among acetone, acetophenone, propanal, acetic acid, acetonitrile will give haloform reaction.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 22.SE, Problem 47AP

Interpretation Introduction