Chemistry: An Atoms First Approach
2nd Edition
ISBN: 9781305079243
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
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Chapter 20, Problem 30E
Interpretation Introduction
Interpretation: It is given that, when an aqueous solution of
Concept introduction: An ion or molecule that leads to the formation of coordination complex due to binding with central atom is known as ligand.
To determine: The reactions and to explain the given observations.
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Given: You weigh out exactly 0.200 g of Fe(NH4)2(SO4)2·6H2O and dissolve it in the 100.00 mL volumetric flask. You then pipette 2.00 mL of this solution into the 50.00 mL volumetric flask to prepare the stock standard tris-bipyridyl-iron(II) solution.
a. Calculate the molar concentration of iron(II) in this solution in the 50.00 mL volumetric flask. (The MW of Fe(NH4)2(SO4)2·6H2O is 392.14 g/mol)
(answer a given the information above)
One of the steps for refining silver involves converting silver into dicyanoargenate(I) ions: 4Ag(s) + 8CN−(aq) + O2(g) + 2H2O(l) ⟶ 4[Ag(CN)2]−(aq) + 4OH−(aq)Explain why oxygen must be present to carry out the reaction. Why does the reaction not occur as: 4Ag(s) + 8CN−(aq) ⟶ 4[Ag(CN)2−(aq)?
Chapter 20 Solutions
Chemistry: An Atoms First Approach
Ch. 20 - What two first-row transition metals have...Ch. 20 - Prob. 2RQCh. 20 - Prob. 3RQCh. 20 - Prob. 4RQCh. 20 - Prob. 5RQCh. 20 - Prob. 6RQCh. 20 - Prob. 7RQCh. 20 - Prob. 8RQCh. 20 - Prob. 9RQCh. 20 - Prob. 10RQ
Ch. 20 - Prob. 1ALQCh. 20 - Prob. 2ALQCh. 20 - Prob. 3ALQCh. 20 - Prob. 4ALQCh. 20 - Prob. 5QCh. 20 - Four different octahedral chromium coordination...Ch. 20 - Prob. 7QCh. 20 - Prob. 8QCh. 20 - Prob. 9QCh. 20 - Prob. 10QCh. 20 - Prob. 11QCh. 20 - Prob. 12QCh. 20 - Prob. 13QCh. 20 - Prob. 14QCh. 20 - Prob. 15QCh. 20 - Prob. 16QCh. 20 - Prob. 17QCh. 20 - Prob. 18QCh. 20 - Prob. 19QCh. 20 - Prob. 20QCh. 20 - Prob. 21ECh. 20 - Prob. 22ECh. 20 - Prob. 23ECh. 20 - Prob. 24ECh. 20 - Prob. 25ECh. 20 - Prob. 26ECh. 20 - Prob. 27ECh. 20 - Prob. 28ECh. 20 - Prob. 29ECh. 20 - Prob. 30ECh. 20 - Prob. 31ECh. 20 - A coordination compound of cobalt(III) contains...Ch. 20 - Prob. 33ECh. 20 - Prob. 34ECh. 20 - Prob. 35ECh. 20 - Prob. 36ECh. 20 - Prob. 37ECh. 20 - Give formulas for the following complex ions. a....Ch. 20 - Prob. 39ECh. 20 - Prob. 40ECh. 20 - Prob. 41ECh. 20 - Amino acids can act as ligands toward transition...Ch. 20 - Prob. 43ECh. 20 - Prob. 44ECh. 20 - Prob. 45ECh. 20 - Prob. 46ECh. 20 - Prob. 47ECh. 20 - Prob. 48ECh. 20 - Prob. 49ECh. 20 - Prob. 50ECh. 20 - Prob. 51ECh. 20 - Prob. 52ECh. 20 - The CrF64 ion is known to have four unpaired...Ch. 20 - Prob. 54ECh. 20 - Prob. 55ECh. 20 - The complex ion Fe(CN)63 is paramagnetic with one...Ch. 20 - Prob. 57ECh. 20 - Prob. 58ECh. 20 - Prob. 59ECh. 20 - Prob. 60ECh. 20 - The wavelength of absorbed electromagnetic...Ch. 20 - The complex ion NiCL42 has two unpaired electrons,...Ch. 20 - How many unpaired electrons are present in the...Ch. 20 - Prob. 64ECh. 20 - Prob. 65ECh. 20 - Prob. 66ECh. 20 - Prob. 67ECh. 20 - Prob. 68ECh. 20 - Silver is sometimes found in nature as large...Ch. 20 - Prob. 70ECh. 20 - Prob. 71AECh. 20 - The compound cisplatin, Pt(NH3)2Cl2, has been...Ch. 20 - Prob. 73AECh. 20 - Prob. 74AECh. 20 - Prob. 75AECh. 20 - Prob. 76AECh. 20 - Prob. 77AECh. 20 - Name the following coordination compounds. a....Ch. 20 - Prob. 79AECh. 20 - Prob. 80AECh. 20 - Carbon monoxide is toxic because it binds more...Ch. 20 - For the process Co(NH3)5Cl2++ClCO(NH3)4Cl2++NH3...Ch. 20 - Prob. 83CWPCh. 20 - Which of the following molecules exhibit(s)...Ch. 20 - Prob. 85CWPCh. 20 - Prob. 86CWPCh. 20 - Prob. 87CWPCh. 20 - Which of the following statement(s) is( are) true?...Ch. 20 - Prob. 89CPCh. 20 - Consider the pseudo-octahedral complex ion of...Ch. 20 - Prob. 91CPCh. 20 - Prob. 92CPCh. 20 - Prob. 93CPCh. 20 - Prob. 94CPCh. 20 - Prob. 95CPCh. 20 - Prob. 96CPCh. 20 - Prob. 97CPCh. 20 - Prob. 98IPCh. 20 - Prob. 99IPCh. 20 - Prob. 100IPCh. 20 - Prob. 101MP
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- Write the net ionic equation for the [CoCl4]?- ion/[Co(H2O)6J²+ ion equilibrium.arrow_forwardWrite the expression for the equilibrium constant Kc for the following equation. FeO(s) + CO(g) ↔ Fe(s) + CO2(g)arrow_forward。 A 0.140 mol quantity of CoCl₂ is added to a liter of 1.20 M NH3 solution. What is the concentration of Co²+ ions at equilibrium? Assume the formation constant* of Co(NH3)² + is 5.0 × 10³¹ M−6. concentration: Marrow_forward
- Cobalt (II) carbonate is slightly soluble in water (Ksp = 1.0 x 10-10). In the presence of an excess of ammonia, Co²+ forms a complex with six ammonia ligands that is somewhat favorable (K₁ = 1.3 x 105). What is the value of the equilibrium constant (Koverall) for the overall reaction that occurs? COCO3 (s) +6 NH3 (aq) → Co(NH)32+ (aq) + CO32- (aq) 1.3 x 10-5 3.6 x 10² 7.7 x 10-16 1.3 x 105 1.0 x 10-10arrow_forwardConsider the insoluble compound cobalt(II) carbonate , CoCO3 . The cobalt(II) ion also forms a complex with ammonia . Write a balanced net ionic equation to show why the solubility of CoCO3 (s) increases in the presence of ammonia and calculate the equilibrium constant for this reaction.For Co(NH3)62+ , Kf = 7.7×104 . Be sure to specify states such as (aq) or (s). + + K =arrow_forwardConsider the insoluble compound cobalt(II) carbonate , CoCO3 . The cobalt(II) ion also forms a complex with ammonia . Write a balanced net ionic equation to show why the solubility of CoCO3 (s) increases in the presence of ammonia and calculate the equilibrium constant for this reaction.For Co(NH3)62+ , Kf = 7.7×104 . Be sure to specify states such as (aq) or (s).arrow_forward
- For [Co(NH3)6]3+ , Kf has a value of 5.00 × 1031. Calculate the concentration of free, uncomplexed Co3+ ions in a solution that contains a total of 0.160 mol/L cobalt III ions and an equilibrium concentration of 0.50 M NH3.arrow_forwardCalculate the equilibrium constant for the reaction: NO2 (g) + NO (g) N2O (g) + O2 (g)arrow_forwardConsider the insoluble compound cobalt(II) carbonate, CoCO3. The cobalt(II) ion also forms a complex with ammonia. Write a balanced net ionic equation to show why the solubility of CoCO3 (s) increases in the presence of ammonia and calculate the equilibrium constant for this reaction. For Co(NH3)62+, Kf = 1.3x105. Be sure to specify states such as (aq) or (s). Knet =arrow_forward
- Consider the insoluble compound cobalt(II) carbonate, CoCO3. The cobalt(II) ion also forms a complex with ammonia. Write a balanced net ionic equation to show why the solubility of CoCO3 (s) increases in the presence of ammonia and calculate the equilibrium constant for this reaction. For Co(NH3)2+, K = 7.7x104. Be sure to specify states such as (aq) or (s). K= Submit Answer Retry Entire Group 3 more group attempts remainingarrow_forwardCalculate the Fe3+ equilibrium concentration when 0.0888 mole of K3[Fe(CN)6] is added to a solution with 0.0.00010 M CN–.arrow_forwardConsider the following expression for the equilibrium constant that represents the dissociation of iodic acid into hydronium and iodate ions. Ka [H3O+] [103] [HIO3] = = 0.161 When 176 g of iodic acid is dissolved in water to give an aqueous solution with a final volume of 1.00 L. Calculate the % dissociation of iodic acid to form iodate anions. The molar mass of iodic acid is 175.91 g mol-¹. a. 0.161% b.16.1% OC. 32.8% Od. 40.1% e. 83.9%arrow_forward
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