Reason for not using frost-free refrigerator to preserve thunderstones has to be identified. Concept Introduction: Vapor pressure is nothing but the pressure of a vapor in contact with its liquid or solid form. When a liquid and vapor are in equilibrium the pressure exerted by the vapor is called the equilibrium vapor pressure. If intermolecular force is small the vapor pressure of the substance is high and the boiling point will be low. The boiling point of a liquid is the temperature at which its vapor pressure is equal to the external pressure.

Question

578,070 J of heat is required to raise the temperature of 15.0 moles of liquid methanol, CH3OH, from 25.0 °C to its boiling point (64.6 °C) and then to completely evaporate the methanol at that temperature. The specific heat of liquid methanol is 2.53 J g^-1 K ^-1 . Calculate the enthalpy of vaporisation of the compound.

Answer 1

Question

Chapter 11, Problem 50SCQ

Interpretation Introduction

Interpretation: Reason for not using frost-free refrigerator to preserve thunderstones has to be identified.

Concept Introduction: Vapor pressure is nothing but the pressure of a vapor in contact with its liquid or solid form.

When a liquid and vapor are in equilibrium the pressure exerted by the vapor is called the equilibrium vapor pressure.

If intermolecular force is small the vapor pressure of the substance is high and the boiling point will be low.

The boiling point of a liquid is the temperature at which its vapor pressure is equal to the external pressure.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Students have asked these similar questions

578,070 J of heat is required to raise the temperature of 15.0 moles of liquid methanol, CH3OH, from 25.0 °C to its boiling point (64.6 °C) and then to completely evaporate the methanol at that temperature. The specific heat of liquid methanol is 2.53 J g^-1 K ^-1 . Calculate the enthalpy of vaporisation of the compound.

compounds that are less harmful to the environment. The heat of vaporization of one such once widely used as refrigerants but are now being replaced by chlorofluorocarbon, tetrafluoroethane (CH₂FCF3), is 22.2 kJ/mol. 1. What mass of tetrafluoroethane must evaporate at its boiling point to freeze 360 g of water initially at 22.0°C? The heat of fusion of water is 6.01 kJ/mol; the specific heat of water is 75.3 J/(mol-'C). Give your answer to three significant figures. 2. How much P-V work is done when 100.0 grams of tetrafluoroethane evaporates at its normal boiling point (-26.30°C) against a constant pressure of 1.00 atm.? The density of liquid tetrafluoroethane at this temperature is 1.206 g/mL. Give your answer to four significant figures. 9 L-atm but are at of v 101. g por the 19

22) Evaporation of sweat requires energy and thus take excess heat away from the body. Some of the water that you drink may eventually be converted into sweat and evaporate. If you drink a 20-ounce bottle of water (590g) that had been in the refrigerator at 3.8 °C, how much heat is needed to convert all of that water into sweat and then to vapor? (Note: Your body temperature is 36.6 °C. For the purpose of solving this problem, assume that the therm properties of sweat are the same as for water. Us, liquid water = 4.184 J/g °C Cs, steam= 1.84 J/g °C C3, ice = 2.09 /g °C AHvap = 40.67 kJ/mol at 36.6 °C. %3D A Hus = 6.01 kJ/mol A) 1420 kJ B) 81 kJ C) 1150 kJ 23) Based on the graph shown below, choose the correct statement about sublimation? Gas Liquid sublimation Solid A) Sublimation is a phase transition from solid to gas B) According to Hess Law, AHsub can be calculated as sum of AHvap and AHUS C) Both A and B are correct