What spectroscopic technique are you going to suggest to a mining company who wishes to determine the metal composition of an ore, and their individual concentrations. The possible metals present are copper, nickel, gold, silver and platinum and this company wants to analyze these metals simultaneously at trace analyte level. Explain why?
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- In the Analytical Chemistry laboratory, one of the B.Sc student Ms. Fatma wanted to analyze the presence of Iron(II) ion in the water samples collected from Sohar Industrial Area in the Sultanate of Oman and analyzed by Spectrophotometric method. (1) 250.00 mL of this water sample (Solution A) known to contain unknown amount of FeSO4. She has diluted Solution A by a dilution factor 10 to make 250.00 mL solution, which she labeled Solution B. Using Spectrophotometer, she has measured the absorbance value (0.642) for Solution B at 508 nm using 1.00 cm cell (cuvet). The molar absorptivity value for Fe2* ion at 508 nm is ɛ508 = 30.8 M-1cm1. (i) What volume of the solution A did she require to make the 250.00 mL of Solution В? (ii) in (i)? What instrument should she use to transfer the volume of the Solution A calculated (ii) Concentration of FeSO4 in Solution B. (iv) Concentration of FeSO4 in Solution A. Mass of FeSO4 in Solution A (Show your calculation) (v)A new analytic instrument is capable of detecting picogram quantities of a chemi-cal substance. How many times more capable is this instrument than one that candetect nanogram quantities of the same chemical?Bone is a biomaterial also referred to hydroxyapatite containing mostly calcium phosphate. Related with the strontium amount analysis of this material, which one correctly states the sample-analyte-analysis, respectively?
- 1. (a) A solution of NaCl is prepared by dissolving 0.0056 g NaCl with enough H2O in a volumetric flask to yield a final volume of 10 mL. Assuming a standard (0.1 mg) analytical balance and class A glassware is employed, calculate the concentration of the solution (M) and its corresponding error. The atomic weights of Na and Cl are 22.98976928(2) and 34.45(1), respectively (the number in parentheses indicating the error in the last digit). (b) What would the error be if a 1mL transfer pipet was employed (10x) rather than the 10 mL volumetric flask?Be sure to answer all parts. Fluorite, a minéral of calcium, is a compound of the metal with fluorine. Analysis shows that a 10.78-g sample of fluorite contains 5.520 g of calcium. Calculate the following: (a) Mass of fluorine in the sample. 19.00 g F (b) Mass fractions of calcium and fluorine in fluorite. Calculate to 3 significant figures. mass fraction Ca mass fraction F (c) Mass percents of calcium and fluorine in fluorite. Calculate to 3 significant figures. mass % Ca mass % FOWLV2 | Online teaching and X 0mySigTau xb Login | bartleby X M COMM.1113: FUND OF ORA X G what food has c - Google Se X + om/ilrm/takeAssignment/takeCovalentActivity.do?locator=assignment-take D [References] hotogray lenses incorporate small amounts of silver chloride in the glass of the lens. When light hits the AgCl particles, the following reaction occurs: hv AgCl Ag + Cl The silver metal that is formed causes the lenses to darken. The enthalpy change for this reaction is 2.90 × 10² kJ/mol. Assuming all this energy must be supplied by light, what is the maximum vavelength of light that can cause this reaction? Wavelength %3D nm Submit Answer Try Another Version 3 item attempts remaining Previous Next
- A chemist obtained the following data for percent lindane in the triplicate analysis of an insecticide preparation: 7.23, 6.95, and 7.53%. Calculate the 90% confidence interval for the mean of the the three data, assuming that (a) the only information about the precision of the method is the precision for the three data. (b) on the basis of long experience with the method, it is believed that s---->σ lindane. (c) If s=0.28 is good estimate of σ, how many replicate measurement should be made in order for the mean for the analysis of sample to be within 0.2% of the true mean 90% of the time.2. The analytical ability of two lab technicians was compared by having each perform analyses for arsenic using the same method on samples having the same origin. For analyst A, s.d. = 0.12%, N=6; and for analyst B, s.d. = 0.06%, N-5. Do these results suggest a difference in the precision of the two chemists?(d) 3-13. Distis me Jum 4 A method of analysis yields weights for gold that are low by 0.4 mg. Calculate the caused by this uncertainty if the weight of gold in the sample is (a) 900 mg. (c) 150 mg. 1-7. The method described in Problem 3-6 is to be used for the analysis of ores that assay about 1.2% gold. What minimum sample weight should be taken if the relative error resulting from a 0.4-mg loss is not to exceed -0.2%? percent relative error (a) (b) (b) 600 mg. (d) 30 mg. 3-14. Wha stan stam 3-15. Сог mea (b) -0.5%? (a) -0.8%? (c) (d) 1.2%? 3.5 3-8. The color change of a chemical indicator requires an overtitration of 0.04 mL. Calculate the percent relative error if the total volume of titrant is (a) 50.00 mL. (c) 25.0 mL. 3-9. A loss of 0.4 mg of Zn occurs in the course of an analysis to determine that element. Calculate the per- cent relative error due to this loss if the weight of Zn in the sample is (a) 40 mg. (c) 400 mg. 3.1 3.1 (b) 10.0 mL. 3.3 2.5 (d) 40.0 mL. Fo (a (E (b) 175…
- II. b) What is the difference between liquid-liquid, solid-liquid and solid-phase extraction? Complete the table below and sort the following examples in the correct column: Steeping tea, washing an organic phase (workup), brewing beer, chemical desalting of crude oil, activated carbon sugar decolorization. liquid-liquid solid-liquid solid-phase Phase that contains analyte before extraction? Phase that contains analyte after extraction? Example(s)Potentially Useful Information Spectrochemical Series: I < Br° < SCN" < cI' < NO3° < F° < OH° < C2O4²- ~ H2O < NCS“ < NH3 < en < PPH3 A student has three test tubes containing a metal (M) nitrate solution M(N03)2 (aq) (where "M" represents a generic transition metal). The student adds aqueous ammonia (NH3) to one test tube, aqueous hydrochloric acid (HCI) to the second tube, and nothing more to the third tube, but forgets to label the tubes. After this, one test tube contains a red solution, one an orange solution, and one a yellow solution. Note: This metal, M, would follow the same rules that we used for Cu(II), Ni(II), and Co(II). The Jahn-Teller Effect does not apply. Complete each statement or answer each question below about the solutions in the three test tubes. The yellow solution contains a coordination complex with... water (H2O) as the ligand. nitrate ion (NO3') as the ligand. chloride ion (Ci") as the ligand. O ammonia (NH3) as the ligand.professor Scimemi has accepted you as a Master’s student and you are involved in a project that studies the cellular basis of neuropsychiatric diseases. For your electrophysiology recordings you have to make a recording solution containing (in mM): 119 NaCl, 2.5 KCl, 2.5 CaCl2, 1 MgCl2, 26.2 NaHCO3, 1 NaH2PO4, 22 glucose. You need 800 ml of it. How much KCl do you need to weigh out? Hint: we only care about KCl here. (MW KCl is 74.55 g/mol