solution of the strong electrolyte KHC2O4 will have pHi, base. (h, An aqueous C20, 16.108 Succinic acid (H2C4H6O4), which we will denote H shown below. At 25 °C, the acid-dissociation constants for is a biologically relevant diprotic acid with the structure 6.9 X 10-5 and Ka2 %3D (a) Determine the pH of a 0.32 M solution of HSuc a 25 °C, assuming that only the first dissociation is relevant. (b) Determine the molar concentration of Suc in the solution in part (a). (c) Is the assumption you made in part (a) justified by the result from part (b)? (d) Will a solution succinic acid are K1 of the salt NaHSuc be acidic, neutral, or basic? Н НО. C. он qiner On8 llot O18(d) 16.109 Butyric acid is responsible for the foul smell of rancid but. ter. The pK, of butyric acid is 4.84. (a) Calculate the pK, for the butyrate ion. (b) Calculate the pH of a 0.050 M solution of butyric acid. (c) Calculate the pH of a 0.050 M solution of sodium butyrate. 16.110 Arrange the following 0.10 M solutions in order of increas- ing acidity: (i) NH,NO3, (ii) NaNO3, (iii) CH3COONH, (V) NaF, (v) CH3COONA. toitibbA 16.111 A 0.25 M solution of a salt NaA has pH = 9,29. What is the ibnl 20.7 value of K, for the parent acid HA? [16.112] The following observations are made about a diprotic acid H2A: (i) A 0.10 M solution of H2A has pH = 3.30. (ii) A 0.10M solution of the salt NaHA is acidic. Which of the follow- ing could be the value of pK2 for H,A; (i) 3,22, (ii) 5.30, (iii) 7.47, or (iy) 9 82?

Chemistry & Chemical Reactivity
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Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter16: Principles Of Chemical Reactivity: The Chemistry Of Acids And Bases
Section: Chapter Questions
Problem 116IL: Amino acids are an important group of compounds. At low pH, both the carboxylic acid group (CO2H)...
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16.110

solution of the strong electrolyte KHC2O4 will have pHi,
base. (h,
An aqueous
C20,
16.108 Succinic acid (H2C4H6O4), which we will denote H
shown below. At 25 °C, the acid-dissociation constants for
is a biologically relevant diprotic acid with the structure
6.9 X 10-5 and Ka2
%3D
(a) Determine the pH of a 0.32 M solution of HSuc a
25 °C, assuming that only the first dissociation is relevant.
(b) Determine the molar concentration of Suc in the
solution in part (a). (c) Is the assumption you made in part
(a) justified by the result from part (b)? (d) Will a solution
succinic acid are K1
of the salt NaHSuc be acidic, neutral, or basic?
Н
НО.
C.
он
qiner
On8
llot
O18(d)
16.109 Butyric acid is responsible for the foul smell of rancid but.
ter. The pK, of butyric acid is 4.84. (a) Calculate the pK, for
the butyrate ion. (b) Calculate the pH of a 0.050 M solution
of butyric acid. (c) Calculate the pH of a 0.050 M solution
of sodium butyrate.
16.110 Arrange the following 0.10 M solutions in order of increas-
ing acidity: (i) NH,NO3, (ii) NaNO3, (iii) CH3COONH, (V)
NaF, (v) CH3COONA.
toitibbA
16.111 A 0.25 M solution of a salt NaA has pH = 9,29. What is the
ibnl 20.7
value of K, for the parent acid HA?
[16.112] The following observations are made about a diprotic acid
H2A: (i) A 0.10 M solution of H2A has pH = 3.30. (ii) A 0.10M
solution of the salt NaHA is acidic. Which of the follow-
ing could be the value of pK2 for H,A; (i) 3,22, (ii) 5.30,
(iii) 7.47, or (iy) 9 82?
Transcribed Image Text:solution of the strong electrolyte KHC2O4 will have pHi, base. (h, An aqueous C20, 16.108 Succinic acid (H2C4H6O4), which we will denote H shown below. At 25 °C, the acid-dissociation constants for is a biologically relevant diprotic acid with the structure 6.9 X 10-5 and Ka2 %3D (a) Determine the pH of a 0.32 M solution of HSuc a 25 °C, assuming that only the first dissociation is relevant. (b) Determine the molar concentration of Suc in the solution in part (a). (c) Is the assumption you made in part (a) justified by the result from part (b)? (d) Will a solution succinic acid are K1 of the salt NaHSuc be acidic, neutral, or basic? Н НО. C. он qiner On8 llot O18(d) 16.109 Butyric acid is responsible for the foul smell of rancid but. ter. The pK, of butyric acid is 4.84. (a) Calculate the pK, for the butyrate ion. (b) Calculate the pH of a 0.050 M solution of butyric acid. (c) Calculate the pH of a 0.050 M solution of sodium butyrate. 16.110 Arrange the following 0.10 M solutions in order of increas- ing acidity: (i) NH,NO3, (ii) NaNO3, (iii) CH3COONH, (V) NaF, (v) CH3COONA. toitibbA 16.111 A 0.25 M solution of a salt NaA has pH = 9,29. What is the ibnl 20.7 value of K, for the parent acid HA? [16.112] The following observations are made about a diprotic acid H2A: (i) A 0.10 M solution of H2A has pH = 3.30. (ii) A 0.10M solution of the salt NaHA is acidic. Which of the follow- ing could be the value of pK2 for H,A; (i) 3,22, (ii) 5.30, (iii) 7.47, or (iy) 9 82?
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