hoose the ompounds

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter16: Synthesis Workshop 1
Section: Chapter Questions
Problem 25CTQ
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Choose the best explanation for why these
compounds are all less than fifteen carbons.
A) Aldehydes with longer alkyl chains
become increasingly nonpolar and the LDF
are stronger than hydrogen bonding with
ethanol.
B) Ethanol molecules will hydrogen bond
with the oxygen of the aldehydes. However,
longer alkyl chains interrupt the ability of
the aldehyde to hydrogen bond with
ethanol which decreases the solubility.
C) Ethanol molecules will form strong LDF
interactions between the alkyl chains of the
aldehydes and the alkyl groups of ethanol.
The strong attractions cause the aldehydes
to precipitate out of solution.
D) When aldehydes chain length increases,
the aldehydes have stronger intermolecular
force with the small ethanol solvent
molecules than the ethanol-ethanol
intermolecular force.
Transcribed Image Text:Choose the best explanation for why these compounds are all less than fifteen carbons. A) Aldehydes with longer alkyl chains become increasingly nonpolar and the LDF are stronger than hydrogen bonding with ethanol. B) Ethanol molecules will hydrogen bond with the oxygen of the aldehydes. However, longer alkyl chains interrupt the ability of the aldehyde to hydrogen bond with ethanol which decreases the solubility. C) Ethanol molecules will form strong LDF interactions between the alkyl chains of the aldehydes and the alkyl groups of ethanol. The strong attractions cause the aldehydes to precipitate out of solution. D) When aldehydes chain length increases, the aldehydes have stronger intermolecular force with the small ethanol solvent molecules than the ethanol-ethanol intermolecular force.
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