Draw a clear scheme for the oxidative addition of H₂ to IrCl(PPh3)3, giving the oxidation state and d-electron count of both the reactant and product.
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- In which solvent, (CH3)2C=O or [(CH3)3C]2C=O, is NaCl more soluble? Explain.Given the following Reaction: 2N2202 (s) + 2H2O (1) ® 4NaOH (s) + O2 (8) DH°= -126 kJ Explain whether this is an endothermic or exothermic reaction. Provide details in your answer.Sodium hypochlorite (NaOCl, the oxidant in household bleach) in aqueous CH3COOH is also touted as a “green” oxidizing agent. For example, oxidation of (CH3)2CHOH with NaOCl forms (CH3)2C = O along with NaCl and H2O. (a) What advantages and/or disadvantages does this method have over oxidation with HCrO4- –Amberlyst A-26 resin? (b) What advantages and/or disadvantages does this method have over oxidation with CrO3, H2SO4, H2O?
- S + Ozle) → SO26) 2 SO2e) + 02 ) → 2 SO31@) SO3e) + H2SO4laq) → H;S;O7(aq) H;S;O7(a) + H2O) → 2 H;SO(aq) (a) What is the oxidation number of S on the products of the first and second equations above? (b) What is being reduced in the second equation? (c) H2S,0, is known as oleum. What is the oxidation state of sulphur in this compound? (d) Is the fourth equation a redox equation? Explain your answer.(b) Give the products for the following chemical reactions. HO SOCI, CHO NACN (H) (D HCNGive the major product(s) of the following oxidation reaction: CIO, H3O* HO
- One of the steps in fat metabolism is the hydration of crotonate to yield 3-hydroxybutyrate. This reaction occurs by addition of —OH to the Si face at C3, followed by protonation at C2, also from the Si face. Draw the product of the reaction, showing the stereochemistry of each step.10. The following reaction has variation of free energy value of AG = -2.1 kJ/mol CH;Br + H2S 2 CH;SH + HBr (a) Calculate Keq at room temperature (25°C) for this reaction as written. (b) Starting with a 1 M solution of CH3B and H2S, calculate the final concentrations of all four species at equilibrium.Please draw the structure of the possible product for the following reaction, and how does the oxidation state of Rh formally change in this reaction? 17. (a) trans-Ir(CO)Cl(PPH3)2 + H2 → (b) H;C-Mn(CO); + P(CH;)Ph2 → (no gas evolved)
- Illustrate the reaction between TiCl4 and CH3OH to form product(s).A white solid is either Pb(NO3)2 or Zn(NO3)2. If an aqueous solution is prepared, which reagent will allow you to distinguish between the two compounds? O KBr O LINO3 Ο ΗΝΟ O CH3CO2H O NH4CIO4Complete the balanced dissociation equation for the compound below in aqueous solution. If the compound does not dissociate, write NR after the reaction arrow. Co(C₂H₃O₂)₂(s)→