Sodium hypochlorite (NaOCl, the oxidant in household bleach) in aqueous CH3COOH is also touted as a “green” oxidizing agent. For example, oxidation of (CH3)2CHOH with NaOCl forms (CH3)2C = O along with NaCl and H2O. (a) What advantages and/or disadvantages does this method have over oxidation with HCrO4- –Amberlyst A-26 resin? (b) What advantages and/or disadvantages does this method have over oxidation with CrO3, H2SO4, H2O?

Sodium hypochlorite (NaOCl, the oxidant in household bleach) in aqueous CH3COOH is also touted as a “green” oxidizing agent. For example, oxidation of (CH3)2CHOH with NaOCl forms (CH3)2C = O along with NaCl and H2O. (a) What advantages and/or disadvantages does this method have over oxidation with HCrO4- –Amberlyst A-26 resin? (b) What advantages and/or disadvantages does this method have over oxidation with CrO3, H2SO4, H2O?

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter19: The Chemistry Of The Main-group Elements

Section: Chapter Questions

Problem 67QRT

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