BDES (kcal/mol):

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Question 6
Given the bond dissociation energies given below (in kcal/mol), estimate the AH° for the propagation step
(CH3)2CH• + Cl2→ (CH3)2CHCI+ Cl•
BDES (kcal/mol):
CH3CH2CH2–H
98
(CH3)2CH–H
95
Cl-Cl
58
H Cl
103
CH3CH2CH2 Cl
81
(CH3)2CH- CI
80
O - 40 kcal/mol
O-22 kcal/mol
O + 45 kcal/mol
O +22 kcal/mol
Transcribed Image Text:Question 6 Given the bond dissociation energies given below (in kcal/mol), estimate the AH° for the propagation step (CH3)2CH• + Cl2→ (CH3)2CHCI+ Cl• BDES (kcal/mol): CH3CH2CH2–H 98 (CH3)2CH–H 95 Cl-Cl 58 H Cl 103 CH3CH2CH2 Cl 81 (CH3)2CH- CI 80 O - 40 kcal/mol O-22 kcal/mol O + 45 kcal/mol O +22 kcal/mol
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