An absorbance calibration curve for Zn was fitted to equation A = 0.913×`Zn, ppm`.   Flask 1: To the first flask, a 1.00 mL aliquot of the unknown Zn solution was diluted to 100.0 mL in a volumetric flask; the absorption intensity from this sample was measured to be A = 0.204.   Flask 2: To a second flask, a 1.00 mL aliquot of the unknown Zn sample and a 1.00 mL aliquot of 10.00 ppm Zn solution were added and diluted to 100.0 mL in a volumetric flask; the absorbance of this sample was measured to be A = 0.294.   Calculate the % spike recovery for the analysis and report to the nearest whole number.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter26: Molecular Absorption Spectrometry
Section: Chapter Questions
Problem 26.32QAP
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An absorbance calibration curve for Zn was fitted to equation A = 0.913×`Zn, ppm`.

 

Flask 1: To the first flask, a 1.00 mL aliquot of the unknown Zn solution was diluted to 100.0 mL in a volumetric flask; the absorption intensity from this sample was measured to be A = 0.204.

 

Flask 2: To a second flask, a 1.00 mL aliquot of the unknown Zn sample and a 1.00 mL aliquot of 10.00 ppm Zn solution were added and diluted to 100.0 mL in a volumetric flask; the absorbance of this sample was measured to be A = 0.294.

 

Calculate the % spike recovery for the analysis and report to the nearest whole number.

 

Hint: A=mC of the type y=mx, so C=A/m

 

%Spike=100%((Cspike-Coriginal)/Cadded))

 

Cadded can be found from C1 V1=Cadded V2.

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