A student obtained the following data for the gas phase decomposition of sulfuryl chloride at 600 K. SO₂Cl₂(g)- →SO₂(g) + Cl₂(g) [SO₂Cl₂], M 1.17x10-3 time, min 0 5.85x10-4 203 2.93x10-4 (1) What is the half-life for the reaction starting at t=0 min? 406 What is the half-life for the reaction starting at t-203 min? (2) is the reaction zero, first, or second order? O min (3) Based on these data, what is the rate constant for the reaction? min Does the half-life increase, decrease or remain constant as the reaction proceeds? 1.47x10-4 609 min¹

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Chapter12: Chemical Kinetics
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Problem 93AE: At 620. K butadiene dimerizes at a moderate rate. The following data were obtained in an experiment...
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A student obtained the following data for the gas phase decomposition of sulfuryl chloride at 600 K.
SO₂Cl₂(g) SO₂(g) + Cl₂(g)
[SO₂Cl₂], M
time, min
1.17x10-3
0
5.85x10-4
203
2.93x10-4
406
(1) What is the half-life for the reaction starting at t=0 min?
What is the half-life for the reaction starting at t=203 min?
(2) is the reaction zero, first, or second order?
min
(3) Based on these data, what is the rate constant for the reaction?
min
1.47x10-4
Does the half-life increase, decrease or remain constant as the reaction proceeds?
609
min¹
Transcribed Image Text:A student obtained the following data for the gas phase decomposition of sulfuryl chloride at 600 K. SO₂Cl₂(g) SO₂(g) + Cl₂(g) [SO₂Cl₂], M time, min 1.17x10-3 0 5.85x10-4 203 2.93x10-4 406 (1) What is the half-life for the reaction starting at t=0 min? What is the half-life for the reaction starting at t=203 min? (2) is the reaction zero, first, or second order? min (3) Based on these data, what is the rate constant for the reaction? min 1.47x10-4 Does the half-life increase, decrease or remain constant as the reaction proceeds? 609 min¹
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