A buffered solution containing dissolved aniline, CH,NH,, and aniline hydrochloride, CH, NH, Cl, has a pH of 5.27. Determine the concentration of CH, NH in the solution if the concentration of CH, NH, is 0.275 M. The pK, of aniline is $ 9.13. [CH_NH] = = Calculate the change in pH of the solution, ApH, if 0.386 g NaOH is added to the buffer for a final volume of 1.35 L. Assume that any contribution of NaOH to the volume is negligible. ApH = M

A buffered solution containing dissolved aniline, CH,NH,, and aniline hydrochloride, CH, NH, Cl, has a pH of 5.27. Determine the concentration of CH, NH in the solution if the concentration of CH, NH, is 0.275 M. The pK, of aniline is $ 9.13. [CH_NH] = = Calculate the change in pH of the solution, ApH, if 0.386 g NaOH is added to the buffer for a final volume of 1.35 L. Assume that any contribution of NaOH to the volume is negligible. ApH = M

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter15: Acid–base Equilibria

Section: Chapter Questions

Problem 57P

See similar textbooks

Similar questions

What is the pH of a buffer that is 0.175 M in a weak acid and 0.200 M in the acids conjugate base? The acids ionization constant is 5.7 104.
A good buffer generally contains relatively equal concentrations of weak acid and conjugate base. If you wanted to buffer a solution at pH = 4.00 or pH = 10.00, how would you decide which weak acidconjugate base or weak baseconjugate acid pair to use? The second characteristic of a good buffer is good buffering capacity. What is the capacity of a buffer? How do the following buffers differ in capacity? How do they differ in pH? 0.01 M acetic acid/0.01 M sodium acetate 0.1 M acetic acid/0.1 M sodium acetate 1.0 M acetic acid/1.0 M sodium acetate
Ka for formic acid is 1.7 104 at 25C. A buffer is made by mixing 529 mL of 0.465 M formic acid, HCHO2, and 494 mL of 0.524 M sodium formate, NaCHO2. Calculate the pH of this solution at 25C after 110 mL of 0.152 M HCl has been added to this buffer.
Enough water is added to the buffer in Question 29 to make the total volume 10.0 L. Calculate (a) the pH of the buffer. (b) the pH of the buffer after the addition of 0.0500 mol of HCl to 0.600 L of diluted buffer. (c) the pH of the buffer after the addition of 0.0500 mol of NaOH to 0.600 L of diluted buffer. (d) Compare your answers to Question 29(a)-(c) with your answers to (a)-(c) in this problem. (e) Comment on the effect of dilution on the pH of a buffer and on its buffer capacity.
A student intends to titrate a solution of a weak monoprotic acid with a sodium hydroxide solution but reverses the two solutions and places the weak acid solution in the buret. After 23.75 mL of the weak acid solution has been added to 50.0 mL of the 0.100 M NaOH solution, the pH of the resulting solution is 10.50. Calculate the original concentration of the solution of weak acid.
When 40.00 mL of a weak monoprotic acid solution is titrated with 0.100-M NaOH, the equivalence point is reached when 35.00 mL base has been added. After 20.00 mL NaOH solution has been added, the titration mixture has a pH of 5.75. Calculate the ionization constant of the acid.
Calculate the pH of a 0.96 M solution of a weak BOH, for instace NH4OH, often written as NH3, and 0.97 M of a salt derived by its conjugate acid, BCl, like NH4Cl. The base dissociation constant, Kb , is 3.86e-6. What is the pH if 35 mL of 0.153 M of a strong acid, like HCl, is added to 100 mL of the buffer solution? What if a strong base, like NaOH, is added with the same ammount instead ? pH ← please insert your values Add acid ___________ Add base ___________
1. You are taking samples at a contaminated mine site from a carbonate aquifer to determine the concentration of dissolved lead in the sample. To preserve the sample, you acidify it to pH 5. How much HCl, in equivalents/L, must be added to this sample to make it pH 5 if the total carbonate concentration is 102 M and the initial pH is 10? Note that the total carbonate is the sum of all of the carbonate species ([H2CO3]+[HCO3] + [CO2]) present in the sample. What are the acid-base pairs responsible for buffering in this sample?
A 0.025 M solution of an unknown organic acid has a pH of 3.23. 2.1 By means of a full calculation, determine the value of the ionisation constant of the conjugatebase of this acid..- You may use “HA” to denote the formula of the acid.- You may make certain assumptions to simplify your calculations2.2 A certain amount of the sodium salt of the conjugate base of the acid was added to the system.Will the pH of the resulting solution increase or decrease, compared to the original given value? Explain your answer in a short sentence or two.
1) In the laboratory, a general chemistry student measured the pH of a 0.554 M aqueous solution of nitrous acid to be 1.787. Use this information she obtained to determine the Ka for this acid? Ka .......................... ? 2) How many grams of solid potassium hydroxide ( molar mass= 56.1 g/mol) are needed to react with 26.7 mL of a 1.75 M hydroiodic acid solution? KOH + HI......> kI + H2o ................ grams
A student wants to make a pH 4.0 buffer solution. She decides to use a buffer made from formic acid and sodium formate (HCOONa). She adds 50.0 grams of sodium formate to a 1 L volumetric flask. The Ka of formic acid is 1.77×10-4. How many mL of 3.0 M formic acid should she add to the 1 L volumetric flask so that when the flask is diluted to the mark the pH will be 4.00?
In each of the following questions, assume that there is no volume change when HCl is added to water in part (a) or the phosphate buffer in part (c). (a) Calculate the pH when 0.091 moles of HCl are added to 1.000 liter of water. (b) What is the difference between the pH of pure water (pH 7.00) and the pH of the solution after HCl was added? (c) Calculate the pH when 0.091 moles of HCl are added to 1.000 liters of a buffer containing 0.352M KH2PO4 and 0.321 M K2HPO4. (d) The pH before the HCl was added is equal to 7.168. What is the difference between the pH before adding the HCl and after adding the HCl?

SEE MORE QUESTIONS

Recommended textbooks for you

Principles of Modern Chemistry

Chemistry

ISBN:

9781305079113

Author:

David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:

Cengage Learning

Chemistry: Principles and Practice

Chemistry

ISBN:

9780534420123

Author:

Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:

Cengage Learning

Chemistry: The Molecular Science

Chemistry

ISBN:

9781285199047

Author:

John W. Moore, Conrad L. Stanitski

Publisher:

Cengage Learning

General Chemistry - Standalone book (MindTap Cour…

Chemistry

ISBN:

9781305580343

Author:

Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell

Publisher:

Cengage Learning

Chemistry: An Atoms First Approach

Chemistry

ISBN:

9781305079243

Author:

Steven S. Zumdahl, Susan A. Zumdahl

Publisher:

Cengage Learning

Chemistry

ISBN:

9781305957404

Author:

Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:

Cengage Learning

Principles of Modern Chemistry

Chemistry

ISBN:

9781305079113

Author:

David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:

Cengage Learning

Chemistry: Principles and Practice

Chemistry

ISBN:

9780534420123

Author:

Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:

Cengage Learning

Chemistry: The Molecular Science

Chemistry

ISBN:

9781285199047

Author:

John W. Moore, Conrad L. Stanitski

Publisher:

Cengage Learning

General Chemistry - Standalone book (MindTap Cour…

Chemistry

ISBN:

9781305580343

Author:

Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell

Publisher:

Cengage Learning

Chemistry: An Atoms First Approach

Chemistry

ISBN:

9781305079243

Author:

Steven S. Zumdahl, Susan A. Zumdahl

Publisher:

Cengage Learning

Chemistry

ISBN: