Chemistry by OpenStax (2015-05-04)
Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Chapter 16, Problem 35E

Given:

P 4 ( s ) + 5 O 2 ( g ) P 4 O 10 ( s ) Δ G ° 298 = 2697.0 kJ / mol

2 H 2 ( g ) + O 2 ( g ) 2 H 2 O ( g ) Δ G ° 298 = 457.18 kJ / mol

6 H 2 O ( g ) + P 4 O 10 ( s ) 4 H 3 PO 4 ( l ) Δ G ° 298 = 428.66 kJ / mol

(a) Determine the standard free energy of formation, Δ G f ° , for phosphoric acid.

(b) How does your calculated result compare to the value in Appendix G? Explain.

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Chapter 16 Solutions

Chemistry by OpenStax (2015-05-04)

Ch. 16 - Consider the system shown in Figure 16.9. What is...Ch. 16 - Arrange the following sets of systems in order of...Ch. 16 - At room temperature, the entropy of the halogens...Ch. 16 - Consider two processes: sublimation of I2(s) and...Ch. 16 - Indicate which substance in the given pairs has...Ch. 16 - Predict the sign of the entropy change for the...Ch. 16 - Predict the sign of the entropy change for the...Ch. 16 - Write the balanced chemical equation for the...Ch. 16 - Write the balanced chemical equation for the...Ch. 16 - What is the difference between S, S , and S 298...Ch. 16 - Calculate S298 for the following changes. (a)...Ch. 16 - Determine the entropy change for the combustion of...Ch. 16 - Determine the entropy change for the combustion of...Ch. 16 - Thermite reactions have been used for welding...Ch. 16 - Using the relevant S 298 values listed in Appendix...Ch. 16 - From the following information, determine S298 for...Ch. 16 - By calculating Suniv, at each temperature,...Ch. 16 - Use the standard entropy data in Appendix G to...Ch. 16 - Use the standard entropy data in Appendix G to...Ch. 16 - What is the difference between G, G, and G 298 for...Ch. 16 - A reaction has H298=100 kj/mol and S298=250 J/mol ...Ch. 16 - Explain what happens as a reaction starts with G0...Ch. 16 - Use the standard free energy of formation data in...Ch. 16 - Use the standard free energy data in Appendix G to...Ch. 16 - Given: P4(s)+5O2(g)P4O10(s)G298=2697.0kJ/mol...Ch. 16 - Is the formation of ozone (O3(g)) from oxygen...Ch. 16 - Consider the decomposition of red mercury(II)...Ch. 16 - Among other things, an ideal fuel for the control...Ch. 16 - Calculate G for each of the following reactions...Ch. 16 - Calculate G for each of the following reactions...Ch. 16 - Calculate the equilibrium constant at 25 C for...Ch. 16 - Calculate the equilibrium constant at 25 C for...Ch. 16 - Calculate the equilibrium constant temperature...Ch. 16 - Calculate the equilibrium constant temperature...Ch. 16 - Consider the following reaction at 298 K:...Ch. 16 - Determine the normal boiling point (in kelvin) of...Ch. 16 - Under what conditions is N2O3(g)NO(g)+NO2(g)...Ch. 16 - At mom temperature, the equilibrium constant (Kw)...Ch. 16 - Hydrogen sulfide is a pollutant found in natural...Ch. 16 - Consider the decomposition of CaCO3(s) into CaO(s)...Ch. 16 - In the laboratory, hydrogen chloride (HCl(g)) and...Ch. 16 - Benzene can be prepared from acetylene....Ch. 16 - Carbon dioxide decomposes into CO and O2 at...Ch. 16 - Carbon tetrachloride, an important industrial...Ch. 16 - Acetic acid, CH3CO2H, can form a dimer,...Ch. 16 - Nitric acid, HNO3, can be prepared by the...Ch. 16 - Determine G for the following reactions. (a)...Ch. 16 - Given that the Gf for Pb2+(aq) and Cl-(aq) is...Ch. 16 - Determine the standard free energy change, Gf, for...Ch. 16 - Determine the standard enthalpy change, entropy...Ch. 16 - The evaporation of one mole of water at 298 K has...Ch. 16 - In glycolysis, the reaction of glucose (Glu) to...Ch. 16 - One of the important reactions in the biochemical...Ch. 16 - Without doing a numerical calculation, determine...Ch. 16 - When ammonium chloride is added to water and...Ch. 16 - An important source of copper is from the copper...Ch. 16 - What happens to G (becomes more negative or more...
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