The following list includes the key terms involved in a radical reaction mechanism. Note - some of the terms below are NOT included in radical mechanisms. Your task is to pick the steps that ARE involved in a radical mechanism and place them in the correct order (from left to right). Use the exact terms below when entering your answer. Propagation Halogenation 1st Step: 2nd Step: 3rd Step: Carbocation Intermediate SN2 Heterolytic Cleavage Termination Concerted Initiation

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
ChapterL4: Proton (1h) Nmr Spectroscopy
Section: Chapter Questions
Problem 15E
icon
Related questions
Question
The following list includes the key terms involved in a radical reaction mechanism. Note - some of the terms below are NOT
included in radical mechanisms. Your task is to pick the steps that ARE involved in a radical mechanism and place them in the
correct order (from left to right). Use the exact terms below when entering your answer.
Propagation Halogenation
1st Step:
2nd Step:
3rd Step:
Carbocation
Intermediate
SN2
Heterolytic
Cleavage
Termination
Concerted
Initiation
Transcribed Image Text:The following list includes the key terms involved in a radical reaction mechanism. Note - some of the terms below are NOT included in radical mechanisms. Your task is to pick the steps that ARE involved in a radical mechanism and place them in the correct order (from left to right). Use the exact terms below when entering your answer. Propagation Halogenation 1st Step: 2nd Step: 3rd Step: Carbocation Intermediate SN2 Heterolytic Cleavage Termination Concerted Initiation
2. READ THE DIRECTIONS TO EACH QUESTION CAREFULLY - not following the directions means you get the question wrong!
3. FORMAT YOUR ANSWERS AS DIRECTED - formatting your answers incorrect means you get the question wrong!
4. Below are the IR regions and NMR chemical shifts table for use with the spectroscopy problems:
¹H NMR
12
R
11 10
OH R
D
H
9
8
7
H
ppm
6
C=C-H
OH
5
NH
H-C-X
H-C-O
-OH
X = F, Cl, Br
(i.e. electronegative atom)
3
-NH
2
H-C-N
H-C-S
CC-H
H-C-C=C
1
H-C-C=O-CH
HC-0
-CH3
-CH₂-
0
4000
DIO
small range
range of values
broad peak
=C-H
N-H
3250-
3300
broad with spikes
-3300
3500
-O-H
broad-3300
-3400
-O-H -CIN
N-H CO
H
=C
ㅏ
2730-
2820
H
3000- 2 peaks
3100
C-H
H
2850-
2960
O
-C-O-H
broad-3000
3000
usually
strong
-CEN
2500
wavenumber, cm-¹
2200
<-CICH
B
2200
2000
H
0
C
0:0
C.
ပြီး
1680
1730
O
OR
1710
1600-
1660
18%0.058
N
1650
viz
NR₂
1600
1500
D
1000
Transcribed Image Text:2. READ THE DIRECTIONS TO EACH QUESTION CAREFULLY - not following the directions means you get the question wrong! 3. FORMAT YOUR ANSWERS AS DIRECTED - formatting your answers incorrect means you get the question wrong! 4. Below are the IR regions and NMR chemical shifts table for use with the spectroscopy problems: ¹H NMR 12 R 11 10 OH R D H 9 8 7 H ppm 6 C=C-H OH 5 NH H-C-X H-C-O -OH X = F, Cl, Br (i.e. electronegative atom) 3 -NH 2 H-C-N H-C-S CC-H H-C-C=C 1 H-C-C=O-CH HC-0 -CH3 -CH₂- 0 4000 DIO small range range of values broad peak =C-H N-H 3250- 3300 broad with spikes -3300 3500 -O-H broad-3300 -3400 -O-H -CIN N-H CO H =C ㅏ 2730- 2820 H 3000- 2 peaks 3100 C-H H 2850- 2960 O -C-O-H broad-3000 3000 usually strong -CEN 2500 wavenumber, cm-¹ 2200 <-CICH B 2200 2000 H 0 C 0:0 C. ပြီး 1680 1730 O OR 1710 1600- 1660 18%0.058 N 1650 viz NR₂ 1600 1500 D 1000
Expert Solution
steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Knowledge Booster
Rate Laws
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:
9780618974122
Author:
Andrei Straumanis
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9781305080485
Author:
John E. McMurry
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9781305580350
Author:
William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:
Cengage Learning
Physical Chemistry
Physical Chemistry
Chemistry
ISBN:
9781133958437
Author:
Ball, David W. (david Warren), BAER, Tomas
Publisher:
Wadsworth Cengage Learning,
Principles of Modern Chemistry
Principles of Modern Chemistry
Chemistry
ISBN:
9781305079113
Author:
David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:
Cengage Learning
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning