Part B.  Activation Energy Temp. Temp. 1/T Reaction Time Rate of Reaction 2.8 x 10-5/time k   oC K K-1 sec. M/sec     40.05 313.20 0.00319 79.40 1.40*10-5     20.0 293.15 0.00341 213.28 5.20*10-6     16.7 289.85 0.00345 155.58 7.14*10-6     9.8 282.95 0.00353 209.90 5.29*10-6     Rate= k[I-]m[BrO3-]n[H+]p Reactant order: m = 2 n=1 p=2 concentration: I = 3.33 x 10-3 ; BrO3 = 6.67 x 10-3;  H+=1.67 x 10-2 Find the rate constant k with proper units

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter20: Kinetics
Section: Chapter Questions
Problem 20.38E: List at least four experimentally determined parameters that you, an experimenter, can define when...
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Part B.  Activation Energy

Temp.

Temp.

1/T

Reaction Time

Rate of Reaction 2.8 x 10-5/time

k

 

oC

K

K-1

sec.

M/sec

 

 

40.05

313.20

0.00319

79.40

1.40*10-5

 

 

20.0

293.15

0.00341

213.28

5.20*10-6

 

 

16.7

289.85

0.00345

155.58

7.14*10-6

 

 

9.8

282.95

0.00353

209.90

5.29*10-6

 

 

Rate= k[I-]m[BrO3-]n[H+]p

Reactant order: m = 2 n=1 p=2

concentration: I = 3.33 x 10-3 ; BrO3 = 6.67 x 10-3;  H+=1.67 x 10-2

Find the rate constant k with proper units

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