Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 6.4, Problem 6.10TIY
(a)
Interpretation Introduction
Interpretation:The rate of appearance of
Concept introduction:
(b)
Interpretation Introduction
Interpretation: The rate of appearance of
Concept introduction: Alkyl halides have the ability to perform nucleophilic substitution reactions.
(c)
Interpretation Introduction
Interpretation: The rate of appearance of
Concept introduction: Alkyl halides have the ability to perform nucleophilic substitution reactions.
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Consider the reaction A + B ¡ C + D. Is each of the following statements true or false? (a) The rate law for the reaction must be Rate = k3A43B4. (b) If the reaction is an elementary reaction, the rate law is second order. (c) If the reaction is an elementary reaction, the rate law of the reverse reaction is first order. (d) The activation energy for the reverse reaction must be greater than that for the forward reaction.
The reaction of CH;OH and HBr is believed to proceed by the mechanism:
ki
CH:OH +H+ = CH:OHz*
k1
Elementary Step 1:
(Fast pre-equilibrium)
Elementary Step 2:
k2
CH;OH2* + Br- 5 CH;Br + H2O
(Slow)
(а)
What is the stoichiometric overall equation for the reaction?
(b)
What is the intermediate in the proposed mechanism?
(c)
Derive the rate law predicted by this mechanism. Show your working out.
(a) Define the following terms:(i) Collision frequency(ii) Rate constant (k)(b) The rate constant of a first order reaction increases from 4 X 10-2 to 24 X 10-2 when the temperature changes from 300 K to 350 K. Calculate the energy of activation (JEa). (log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021, log 6 = 0.7782)
Chapter 6 Solutions
Organic Chemistry: Structure and Function
Ch. 6.2 - Prob. 6.1ECh. 6.2 - Prob. 6.3TIYCh. 6.3 - Prob. 6.4ECh. 6.3 - Prob. 6.5ECh. 6.3 - Prob. 6.6ECh. 6.3 - Prob. 6.7ECh. 6.3 - Prob. 6.8ECh. 6.4 - Prob. 6.10TIYCh. 6.4 - Prob. 6.11ECh. 6.5 - Prob. 6.12E
Ch. 6.5 - Prob. 6.13ECh. 6.6 - Prob. 6.14ECh. 6.6 - Prob. 6.16TIYCh. 6.6 - Prob. 6.17ECh. 6.7 - Prob. 6.18ECh. 6.7 - Prob. 6.19ECh. 6.7 - Prob. 6.20ECh. 6.8 - Prob. 6.21ECh. 6.8 - Prob. 6.22ECh. 6.8 - Prob. 6.23ECh. 6.8 - Prob. 6.24ECh. 6.9 - Prob. 6.26TIYCh. 6.10 - Prob. 6.27ECh. 6.10 - Prob. 6.28ECh. 6 - Prob. 31PCh. 6 - Prob. 32PCh. 6 - Prob. 33PCh. 6 - Prob. 34PCh. 6 - Prob. 35PCh. 6 - Prob. 36PCh. 6 - Prob. 37PCh. 6 - Prob. 38PCh. 6 - Prob. 39PCh. 6 - Prob. 40PCh. 6 - Prob. 41PCh. 6 - Prob. 42PCh. 6 - Prob. 43PCh. 6 - Prob. 44PCh. 6 - Prob. 45PCh. 6 - Prob. 46PCh. 6 - Prob. 47PCh. 6 - Prob. 48PCh. 6 - Prob. 49PCh. 6 - Prob. 50PCh. 6 - Prob. 51PCh. 6 - Prob. 52PCh. 6 - Prob. 53PCh. 6 - Prob. 54PCh. 6 - Prob. 55PCh. 6 - Prob. 56PCh. 6 - Prob. 57PCh. 6 - Prob. 58PCh. 6 - Prob. 59PCh. 6 - Prob. 60PCh. 6 - Prob. 61PCh. 6 - Prob. 62PCh. 6 - Prob. 63PCh. 6 - Prob. 64PCh. 6 - Prob. 65PCh. 6 - Prob. 66PCh. 6 - Prob. 67PCh. 6 - Prob. 68P
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