An Introduction to Thermal Physics
1st Edition
ISBN: 9780201380279
Author: Daniel V. Schroeder
Publisher: Addison Wesley
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Chapter 5.2, Problem 18P
To determine
The reason why the energy of the system tends to spontaneously decrease.
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Check out a sample textbook solutionChapter 5 Solutions
An Introduction to Thermal Physics
Ch. 5.1 - Prob. 1PCh. 5.1 - Consider the production of ammonia from nitrogen...Ch. 5.1 - Prob. 3PCh. 5.1 - Prob. 4PCh. 5.1 - Consider a fuel cell that uses methane (natural...Ch. 5.1 - Prob. 6PCh. 5.1 - The metabolism of a glucose molecule (see previous...Ch. 5.1 - Derive the thermodynamic identity for G (equation...Ch. 5.1 - Sketch a qualitatively accurate graph of G vs. T...Ch. 5.1 - Suppose you have a mole of water at 25C and...
Ch. 5.1 - Suppose that a hydrogen fuel cell, as described in...Ch. 5.1 - Prob. 12PCh. 5.1 - Prob. 13PCh. 5.1 - Prob. 14PCh. 5.1 - Prob. 15PCh. 5.1 - Prob. 16PCh. 5.1 - Prob. 17PCh. 5.2 - Prob. 18PCh. 5.2 - In the previous section 1 derived the formula...Ch. 5.2 - Prob. 20PCh. 5.2 - Is heat capacity (C) extensive or intensive? What...Ch. 5.2 - Prob. 22PCh. 5.2 - Prob. 23PCh. 5.3 - Go through the arithmetic to verify that diamond...Ch. 5.3 - Prob. 25PCh. 5.3 - How can diamond ever be more stable than graphite,...Ch. 5.3 - Prob. 27PCh. 5.3 - Calcium carbonate, CaCO3, has two common...Ch. 5.3 - Aluminum silicate, Al2SiO5, has three different...Ch. 5.3 - Sketch qualitatively accurate graphs of G vs. T...Ch. 5.3 - Sketch qualitatively accurate graphs of G vs. P...Ch. 5.3 - The density of ice is 917kg/m3. (a) Use the...Ch. 5.3 - An inventor proposes to make a heat engine using...Ch. 5.3 - Below 0.3 K the Slope of the 3He solid–liquid...Ch. 5.3 - Prob. 35PCh. 5.3 - Effect of altitude on boiling water. (a) Use the...Ch. 5.3 - Prob. 37PCh. 5.3 - Prob. 38PCh. 5.3 - Prob. 39PCh. 5.3 - The methods of this section can also be applied to...Ch. 5.3 - Suppose you have a liquid (say, water) in...Ch. 5.3 - Ordinarily, the partial pressure of water vapor in...Ch. 5.3 - Assume that the air you exhale is at 35C, with a...Ch. 5.3 - Prob. 44PCh. 5.3 - Prob. 46PCh. 5.3 - Prob. 47PCh. 5.3 - Prob. 48PCh. 5.3 - Prob. 49PCh. 5.3 - The compression factor of a fluid is defined as...Ch. 5.3 - Prob. 51PCh. 5.3 - Prob. 52PCh. 5.3 - Repeat the preceding problem for T/Tc=0.8.Ch. 5.3 - Prob. 54PCh. 5.3 - Prob. 55PCh. 5.4 - Prove that the entropy of mixing of an ideal...Ch. 5.4 - In this problem you will model the mixing energy...Ch. 5.4 - Suppose you cool a mixture of 50% nitrogen and 50%...Ch. 5.4 - Suppose you start with a liquid mixture of 60%...Ch. 5.4 - Suppose you need a tank of oxygen that is 95%...Ch. 5.4 - Prob. 62PCh. 5.4 - Everything in this section assumes that the total...Ch. 5.4 - Figure 5.32 shows the phase diagram of plagioclase...Ch. 5.4 - Prob. 65PCh. 5.4 - Prob. 66PCh. 5.4 - Prob. 67PCh. 5.4 - Plumbers solder is composed of 67% lead and 33%...Ch. 5.4 - What happens when you spread salt crystals over an...Ch. 5.4 - What happens when you add salt to the ice bath in...Ch. 5.4 - Figure 5.35 (left) shows the free energy curves at...Ch. 5.4 - Repeat the previous problem for the diagram in...Ch. 5.5 - If expression 5.68 is correct, it must be...Ch. 5.5 - Prob. 74PCh. 5.5 - Compare expression 5.68 for the Gibbs free energy...Ch. 5.5 - Seawater has a salinity of 3.5%, meaning that if...Ch. 5.5 - Osmotic pressure measurements can be used to...Ch. 5.5 - Because osmotic pressures can be quite large, you...Ch. 5.5 - Most pasta recipes instruct you to add a teaspoon...Ch. 5.5 - Use the Clausius–Clapeyron relation to derive...Ch. 5.5 - Prob. 81PCh. 5.5 - Use the result of the previous problem to...Ch. 5.6 - Prob. 83PCh. 5.6 - Prob. 84PCh. 5.6 - Prob. 85PCh. 5.6 - Prob. 86PCh. 5.6 - Sulfuric acid, H2SO4, readily dissociates into H+...Ch. 5.6 - Prob. 88PCh. 5.6 - Prob. 89PCh. 5.6 - When solid quartz dissolves in water, it combines...Ch. 5.6 - When carbon dioxide dissolves in water,...Ch. 5.6 - Prob. 92P
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- At the start of a basketball game, a referee tosses a basketball straight into the air by giving it some initial speed. After being given that speed, the ball reaches a maximum height of 4.25 m above where it started. Using conservation of energy, find a. the balls initial speed and b. the height of the ball when it has a speed of 2.5 m/s.arrow_forwardThe Flybar high-tech pogo stick is advertised as being capable of launching jumpers up to 6 ft. The ad says that the minimum weight of a jumper is 120 lb and the maximum weight is 250 lb. It also says that the pogo stick uses a patented system of elastometric rubber springs that provides up to 1200 lbs of thrust, something common helical spring sticks simply cannot achieve (rubber has 10 times the energy storing capability of steel). a. Use Figure P8.32 to estimate the maximum compression of the pogo sticks spring. Include the uncertainty in your estimate. b. What is the effective spring constant of the elastometric rubber springs? Comment on the claim that rubber has 10 times the energy-storing capability of steel. c. Check the ads claim that the maximum height a jumper can achieve is 6 ft.arrow_forwardCheck Your Understanding There is a second solution to the system of equations solved in this example (because the energy equation is quadratic): v1.f=-2.5m/s , v2.f=0 . This solution is unacceptable on physical grounds; what’s with it?arrow_forward
- A block is placed on top of a vertical spring, and the spring compresses. Figure P8.24 depicts a moment in time when the spring is compressed by an amount h. a. To calculate the change in the gravitational and elastic potential energies, what must be included in the system? b. Find an expression for the change in the systems potential energy in terms of the parameters shown in Figure P8.24. c. If m = 0.865 kg and k = 125 N/m, find the change in the systems potential energy when the blocks displacement is h = 0.0650 m, relative to its initial position. FIGURE P8.24arrow_forwardA ball of clay falls freely to the hard floor. It does not bounce noticeably, and it very quickly comes to rest. What, then, has happened to the energy the ball had while it was falling? (a) It has been used up in producing the downward motion. (b) It has been transformed back into potential energy. (c) It has been transferred into the ball by heat. (d) It is in the ball and floor (and walls) as energy of invisible molecular motion. (e) Most of it went into sound.arrow_forwardA boy starts at rest and slides down a frictionless slide as in Figure P5.64. The bottom of the track is a height h above the ground. The boy then leaves the track horizontally, striking the ground a distance d as shown. Using energy methods, determine the initial height H of the boy in terms of h and d. Figure P5.64arrow_forward
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