Interpretation:
The equilibrium constant for the dissociation of
Concept Introduction:
The dissociation of
The equilibrium constant for the dissociation of
Where,
The expression for the translational partition function is given below.
Where,
The expression for rotational partition function is given below.
Where,
The expression for vibrational partition function is given below.
Where,
Answer to Problem 12.14P
The equilibrium constant for the dissociation of
Explanation of Solution
The equilibrium constant for the dissociation of
The partition functions of
The translational partition function for
Given,
The translational partition function for
Given,
Rotational partition function for
Given,
Vibrational partition function for
Given,
Therefore the equilibrium constant can be calculated by substituting these valus in the equation as follows,
Given,
The equilibrium constant for the dissociation of
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Chapter 12 Solutions
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