Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 13, Problem 3CTQ
Interpretation Introduction
Interpretation:The curved arrow needs to be used to represent the one-step mechanism for substitution reaction in given model-1.
Concept Introduction: A curved arrow is used to explain the movement of electrons or attack by different groups in an organic reaction mechanism which results in the formation of different products. The attack always takes place from negative to positive or it can be said that it takes place from electron rich group to electron deficient group.
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Follow the curved arrows and draw the product of this reaction.
. You do not have to consider stereochemistry.
Draw a mechanism for the reaction of methylamine with formic acid. In the box to the left, draw any necessary curved arrows. Show the products of the reaction in the box to the right. Include any nonzero formal charges and all lone pairs of electrons. Finally, check the box to indicate which side of the reaction is favored at equilibrium.
Draw a complete, step-wise, curved arrow mechanism for each reaction shown below. You don't need to worry about
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It may help if you take the following steps.
1) Find the nucleophile and the electrophile.
2) Determine the major functional group present in the nucleophile and electrophile.
3) Determine the type of reaction this particular nucleophile/electrophile pair is likely to participate in
4) Draw the mechanism that corresponds with this reaction type.
a)
OH
cat. H2SO4
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b)
:OH
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Organic Chemistry: A Guided Inquiry
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