For problem 7, the major mono chlorination product obtained on disregarding stereoisomers should be given Concept introduction: Distribution of products based on Probability and Reactivity: Depending on the relative rate of alkyl radical formation, the type of chlorination product obtained differs. At room temperature, it is 5.00 times easier for a chlorine radical to form a tertiary radical than a primary radical, and it is 3.8 times easier to form a secondary radical than a primary radical. These, ratios differ at different temperatures
For problem 7, the major mono chlorination product obtained on disregarding stereoisomers should be given Concept introduction: Distribution of products based on Probability and Reactivity: Depending on the relative rate of alkyl radical formation, the type of chlorination product obtained differs. At room temperature, it is 5.00 times easier for a chlorine radical to form a tertiary radical than a primary radical, and it is 3.8 times easier to form a secondary radical than a primary radical. These, ratios differ at different temperatures
Solution Summary: The author explains the distribution of products based on Probability and Reactivity: Depending on the relative rate of alkyl radical formation, the type of chlorination product differs.
For problem 7, the major mono chlorination product obtained on disregarding stereoisomers should be given
Concept introduction:
Distribution of products based on Probability and Reactivity:
Depending on the relative rate of alkyl radical formation, the type of chlorination product obtained differs. At room temperature, it is 5.00 times easier for a chlorine radical to form a tertiary radical than a primary radical, and it is 3.8 times easier to form a secondary radical than a primary radical. These, ratios differ at different temperatures
(b)
Interpretation Introduction
Interpretation:
The percentage yield of the major product should be calculated.
Concept introduction:
Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.
chlorine radical forms a tertiary radical five times faster than a primary radical and it forms a secondary radical 3.8 times faster than a primary radical.
Relative rates of alkyl radical formation by a chlorine radical at 125 °C.