Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Question
Show work. Don't give Ai generated solution
Transcribed Image Text:5.
о
O
O
s) Which of the following statements is/are true? Select all that apply.
CH3NH2 can act as a Brønsted-Lowry base, Lewis base, Brønsted-Lowry acid, or Lewis acid.
Lewis bases are electron-pair donors; Lewis acids are electron-pair acceptors.
In the reaction, (CH3) C + Br (CH3) CBr, the carbocation acts as both a Lewis acid and Brønsted-Lowry
acid.
A Lewis acid is also called a nucleophile.
In the reaction, CH,O + CH3CH₂CICH,CH₂OCH3 + CI, CH₂O" acts as a nucleophile.
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by stepSolved in 2 steps with 2 images
Knowledge Booster
Similar questions
- For conjugate acidbase pairs, how are Ka and Kb related? Consider the reaction of acetic acid in water CH3CO2H(aq)+H2O(l)CH3CO2(aq)+H3O+(aq) where Ka = 1.8 105 a. Which two bases are competing for the proton? b. Which is the stronger base? c. In light of your answer to part b. why do we classify the acetate ion (CH3CO2) as a weak base? Use an appropriate reaction to justify your answer. In general, as base strength increases, conjugate acid strength decreases. Explain why the conjugate acid of the weak base NH3 is a weak acid. To summarize, the conjugate base of a weak acid is a weak base and the conjugate acid of a weak base is a weak acid (weak gives you weak). Assuming Ka for a monoprotic strong acid is 1 106, calculate Kb for the conjugate base of this strong acid. Why do conjugate bases of strong acids have no basic properties in water? List the conjugate bases of the six common strong acids. To tie it all together, some instructors have students think of Li+, K+, Rb+, Cs+, Ca2+, Sr2+, and Ba2+ as the conjugate acids of the strong bases LiOH, KOH. RbOH, CsOH, Ca(OH)2, Sr(OH)2, and Ba(OH)2. Although not technically correct, the conjugate acid strength of these cations is similar to the conjugate base strength of the strong acids. That is, these cations have no acidic properties in water; similarly, the conjugate bases of strong acids have no basic properties (strong gives you worthless). Fill in the blanks with the correct response. The conjugate base of a weak acid is a_____base. The conjugate acid of a weak base is a_____acid. The conjugate base of a strong acid is a_____base. The conjugate acid of a strong base is a_____ acid. (Hint: Weak gives you weak and strong gives you worthless.)arrow_forwardTable 13-4 lists the stepwise Ka values for some polyprotic acids. What is the difference between a monoprotic acid, a diprotic acid, and a triprotic acid? Most polyprotic acids are weak acids; the major exception is H2SO4. To solve for the pH of a solution of H2SO4, you must generally solve a strong acid problem as well as a weak acid problem. Explain. Write out the reactions that refer to Ka1 and Ka2 for H2SO4. For H3PO4, Ka1 = 7.5 103, Ka2 = 6.2 108, and Ka3= 4.8 1013. Write out the reactions that refer to the Ka1, Ka2and Ka3equilibrium constants. What are the three acids in a solution of H3PO4? Which acid is strongest? What are the three conjugate bases in a solution of H3PO4? Which conjugate base is strongest? Summarize the strategy for calculating the pH of a polyprotic acid in water.arrow_forwardFind the value of Kb for the conjugate base of the following organic acids. (a) picric acid used in the manufacture of explosives; Ka = 0.16 (b) trichloroacetic acid used in the treatment of warts; Ka = 0.20arrow_forward
- In the following reaction of tetrafluoroboric acid, HBF4, with the acetate ion, C2H3O2, the formation of tetrafluoroborate ion, BF4 , and acetic acid, HC2H3O2 is favored. HBF4+C2H3O2BF4+HC2H3O2 Which is the weaker base, BF4 or acetate ion?arrow_forwardPlease provide explarrow_forwardConsider the following acidic equilibrium: H₂CO₃(aq) + H₂O(l) ⇌ HCO₃⁻(aq) + H₃O⁺(aq). If you add NaHCO₃ to this solution, which of the following will occur? A) The reaction quotient will decrease. B) The reaction will shift in the reverse direction. C) The equilibrium constant will increase. D) No changes to the equilibrium positions will take place.arrow_forward
- CH3CH2COOH Draw the Lewis structure of the acid and mark the acidic hydrogen with an asterisk (*). Draw a Lewis structure of the conjugate base of the acid. Suppose the acid is neutralized with a strong base. a) Which of the two structures you drew in 6 and 7 would be the predominant form of the species at a pH well above that at the equivalence point? b) Which of the two structures would be the predominant form of the species at a very low pH, well below that at the equivalence point and similar to the pH near the start of the titration? c) At what point in the titration, if any, would there be equal amounts of the two forms?arrow_forward. (a) Combine the following equations to construct an acid-base reaction equation, in the process drawing complete Lewis structures for both reactants and products, along with arrows to show the movement of nonbonded electrons. (b) Predict the overall direction of equilibrium in your equation and justify your answer. (c) Calculate the pK, values for the conjugate bases of the acids in your equation. NH t H20 H30® CHy Cita OH +Ho 1300 + CHzchb0s pka =15:9 + NH3 pkw =9.24arrow_forwardThree acids found in foods are lactic acid, LA, (in milk products), oxalic acid, OA, (in rhubarb), and malic acid, MA (in apples). The pKa values are LA =3.88, OA =1.23, and MA =3.40. Which list has the conjugate bases of these acids, lactate, oxalate, and malate, in order of decreasing strength? O lactate > malate > oxalate lactate > oxalate > malate malate > lactate > oxalate oxalate > malate > lactatearrow_forward
- COHSOH(ag) + H2On + CeHsO (aq) + H3O*(a9) Ka= 1.12 x 10-10 (a) Phenol is a weak acid that partially dissociates in water according to the equation above. Write the equilibrium-constant expression for the dissociation of the acid in water. (b) What is the pH of a 0.75 M CaHsOH(ag) solution? (C) For a certain reaction involving CaHsOH(ag) to proceed at a significant rate, the phenol must be primarily in its deprotonated form, C3H5O (eg). In order to ensure that the CsHsOH(aq) is deprotonated, the reaction must be conducted in a buffered solution. On the number scale below, circle each pH for which more than 50 percent of the phenol molecules are in the deprotonated form (CoHsO (aq). Justify your answer. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 Justification: (d) CeHsOH(ag) reacts with NaOH(ag). Write a net ionic equation representing this reaction (aka: invasion equation). (e) What is the pH of the resulting solution when 30 mL of 0.40 M CSH5OH(aq) is added to 25 mL of 0.60 M NAOH. Show all work…arrow_forwardThe acid-dissociation constant for benzoic acid (C6H5COOH) is 6.3×10−5. Part A Calculate the equilibrium concentration of H3O+ in the solution if the initial concentration of C6H5COOH is 0.060 M . Express your answer using two significant figures. part B Calculate the equilibrium concentration of C6H5COO−C6H5COO− in the solution if the initial concentration of C6H5COOHC6H5COOH is 0.060 MM . Express your answer using two significant figures.arrow_forwardPlease answer these questions on your Page 8 (a) HA(aq) is a weak acid with a dissociation constant, Ka, of 7.7 x 10-¹2. What is the pH of a 0.011 M solution of A-(aq)? The temperature is 25°C. (b) For the reaction A(g) A(1), the equilibrium constant is 0.666 at 25.0°C and 0.111 at 75.0°C. Making the approximation that the entropy and enthalpy changes of this reaction do not change with temperature, at what temperature will the equilibrium constant be equal to 0.777?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning 
General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning