Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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(a) assign R or S configuration to each chiral center,
(b) Which compound are enantiomers?
(c) Which compounds are diastereomers?
The two different enantiomers of Carvone have a distinctly different aroma (one Caraway the other spearmint). Explain why our sense of smell can distinguish between the enantiomers?
Like carvone, the two enantiomers of celery ketone smell different. The R enantiomer smells like celery leaves, whereas the S enantiomer smells like licorice. Draw each enantiomer and assign its odor.
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- C. Smelling Chirality. Carvone Olfactory receptors in our noses, used for the detection of odors, are chiral. Therefore, in some cases, we can tell the difference between enantiomers by their odor. Carvone is one such compound that we can distinguish between the R and S enantiomer by their odor. 1. Identify the chiral center in carvone and draw the R and S enantiomers in the indicated boxes. 2. Smell both of the enantiomers of carvone and provide a brief description of their odors in the same boxes. Carvone is perfectly safe to smell as both enantiomers are found in various foods. R-carvone S-carvonearrow_forwardDraw both enantiomers of clopidogrel (trade name Plavix), a drug given to prevent the formation of blood clots in persons who have a history of stroke or coronary artery disease. Plavix is sold as a single enantiomer with the S configuration. Which enantiomer is Plavix?arrow_forwardClassify each compound as identical to A or its enantiomer.arrow_forward
- What is the chiral center in each compound. R or Sarrow_forwardDoes methylcyclopentane have a stereogenic center?arrow_forward1. An object is chiral if it A. is superimposable on its mirror image B. is not superimposable on its mirror image C. has no mirror image D. is identical to each mirror image of itselfarrow_forward
- Which of the following must be true for an optically active compound? the molecular configuration is achiral O b. the molecular configuration is chiral O c. the molecular configuration must have two or more stereogenic centers d. the compound is a racemic mixture of enantiomersarrow_forwardExplain each statement by referring to compounds A-E. он он HO .OH CI OH A в E a. A has a mirror image but no enantiomer. b. B has an enantiomer and no diastereomer. c. C has both an enantiomer and a diastereomer. d. D has a diastereomer but no enatiomer. e. E has a diastereomer but no enantiomer. E..arrow_forwardidentify whether the two structures in each pair represents enantiomets or two molecules of the same compound in different orientation.arrow_forward
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