Chapter 5.1, Problem 3CC

Draw the structure of a molecule that fi ts each description: a. a 2 ° alcohol of molecular formula C 6H 14O b. an ether with molecular formula C 6H 14O that has a methyl group bonded to oxygen c. a 3 ° alkyl halide with molecular formula C 5H 11Br

73. O-hydroxybenzoic acid.is a major product formed with phenol and which other reactant/s? I-primary alcohol Il-sodium hydroxide Ill-water IV-carbon dioxide A. I and III B. I and IV C. II and III D. II and IV 74. How many substitution product/s is/are formed when metabromo anisole is treated with ammonia? A. 0 no reaction B. 1 C. 2 D. 3 75. Butan-1-ol is formed from which of the following reactant-reaction pair? A. Butanal-reduction reaction B. Butanone - reduction reaction C. Butanoic acid oxidation reaction D. Butene- dehydration reaction 76. Dienone phenol rearrangement reaction belongs to which type of reaction? A. Neutral B. Acid-catalyzed reaction C. Base catalyzed reaction D. Neither of the given choices 77. Evaluate the given statements: In SNI the first step involves the formation of a carbocation. Afterward, the carbocation is attacked by an electrophile. A. Only the first statement is correct. B. Only the second statement is correct. C. Both statements are correct.

6. What is the product? CH3 осно A. C. A and B A. A B. B C. C CH3 B. DBN CH₂

CH3–C–CH2-CH3 For the compound: a. Circle the carbonyl group in the compound above. b. What is the geometry of the carbon atom of the carbonyl group? What is the hybridization of the carbonyl carbon (sp, sp² or sp³)?. d. Is the compound soluble or insoluble in water? e. Is the compound more or less soluble (in water) than an alcohol? f. Does this compound have a higher or lower bp than an alkane? С.

What are the systematic (IUPAC) names for the compounds shown? A. OH H3C systematic (IUPAC) name: B. H3C-CH₂-CH-CH₂ LL CH3 OH systematic (IUPAC) name:

Give the IUPAC name for each compound. CH3 CH2CH3 Br a. PHCH(CH3)2 b. С. d.

Draw the structure of all compounds that t the following descriptions.a. ve constitutional isomers having the molecular formula C4H8b. nine constitutional isomers having the molecular formula C7H16c. twelve constitutional isomers having the molecular formula C6H12 and containing one ring

B. Give the IUPAC name for each compound. F CH3 ÇI 1. CH;CH2CHCH2CH2CHCH3 5. CH,CH3 F 2. CI 6. OH CI NO, 7. NO, NO, Br 8. Br 3.

a. What hydrocarbon with molecular formula C4H10 forms only two monochlorinated products? Both products are achiral. b. What hydrocarbon with the same molecular formula as in part a forms three monochlorinated products? One is achiral and two are chiral.