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Modern Physics for Scientists and Engineers
4th Edition
ISBN: 9781133103721
Author: Stephen T. Thornton, Andrew Rex
Publisher: Cengage Learning
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How do the allowed orbits for electrons in atoms differ from the allowed orbits for planets around the sun? Explain how the correspondence principle applies here.
One can now use integrated-circuit technology to manufacture a "box" that traps electrons in a region only a few nanometers wide. Imagine that we make an essentially one-dimensional box with a length of 3 nanometers. Suppose we put 10 electrons in such a box and allow them to settle into the lowest possible energy states consistent with the Pauli exclusion principle.
a) What will be the value of the highest energy level occupied by at least one electron?
b) What will be the electrons' total energy (ignoring their electrostatic repulsion)?
c) How would your answers to the above be different if the electrons were bosons instead of fermions?
d) What is the wavelength of the lowest energy photon that can be absorbed (the electrons in this box are fermions)?
·Shown here is the visible part of the spectrum of some gas. There are 11 lines. There could be
6.
more, they just aren't in the wavelength range of the spectrum. The wavelength increases toward the
right. :..
de
f
gh
k
(a) Which line or lines correspond(s) to the two closest spaced energy levels? Explain.
(b) Which line or lines correspond(s) to the two farthest spaced energy levels? Explain.
(c) What is the minimum number of energy levels in an atom of the gas that could produce the lines in
this spectrum? Explain.
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- The Lennard-Jones parameters for argon are: A = 1.022 x 10-7 J m° and B = 1.579 x 10-134 J m12. Calculate the distance at which the energy will be minimum and calculate the minimum energy. Draw the energy profile also. I.arrow_forwardFirst consider some simple electronic partition functions: a. Consider a two-level system of N particles separated by an energy of hv. i. Derive expressions for ē, E, and P, as a function of T. P, is the probability that the system is in the higher energy level. ii. What are the limiting values for each of these at T = 0 and kT » hv. iii. For a level spacing 200 cm what is T when Ē = Nhv. iv. What is P, at the T found in part iii?arrow_forwardConsider a cavity with a volume of 1cc and the frequency range 0 to 473 THz. Assume a refractive index of unity. a. What is the total number of optical modes contained in this cavity? b. What is the mode density (modes/k/m3) at 473 THz? c. If a Neon atom is placed in this cavity which has an emission at 473 THz with a 16 MHz linewidth, how many modes can the atom couple to? d. How small would the cavity have to be in order to have the number of modes coupled to equal 100?arrow_forward
- a. For the allowed energies of a particle in a box to be large, should the box be very big or very small? Explain.b. Which is likely to have larger values for the allowed energies: an atom in a molecule, an electron in an atom, or a proton in a nucleus? Explain.arrow_forwarda) How many ways are there to arrange 3 quanta among 4 atoms in a solid? b) . the ground state energy. What is the Boltzmann factor for this excited state? >At room temperature, the fourth excited state of a microscopic oscillator is o.6 eV abovearrow_forwardConsider the Balmer series discussed in the book (and Prof. Scherer's lecture notes), where the frequencies are given by: x (3.29 × 1015 s-1) n = 3,4,5, .. v = Let us focus only on the spectral lines and transitions corresponding to the Balmer series. a) Suppose the Balmer series of hydrogen is studied using a Franck-Hertz experiment. What is the threshold voltage required for n=3? How about n=4? b) The Lyman Series frequencies are given by v = |1- x (3.29 x 1015 s-1). Describe what is different about these two series of emission frequencies of photons from the hydrogen atom? That is, what distinguishes one series from the other? (Hint: it may help to think about the Bohr model interpretation of transitions.)arrow_forward
- Q1: Consider the ideal laser medium behaves as a four-level system and the population inversion between states 2 and 3. The pump excites the atoms to states 3 and 2 at a rate pumping R3 and R₂, respectively. State 4 decays back to 3 so fast. What is the pump rate in the absence of the saturating beam and no oscillation on the state 3? Assume that the degeneracies in all states are different.arrow_forwardThe radial wave function for the 5f orbital can be expressed as: Rn (r) = Ne-r/5 p3 (8-4) where N is a normalization constant. a. What is n? n = a. What is l? = c. How many nodes does this wave function have? # nodes= d. Compute the numerical value of the integral Jo I 2 Rn,Kr) Rn,(r) dr :arrow_forwardAI answered the problem this way. Is this correct? From the text you've provided, it seems like the problem at hand is to calculate the wavelength of a photon emitted when singly ionized helium (He+) transitions from the n=3n=3 to n=2n=2 state. Since He+ is a single-electron ion, it behaves like a hydrogen atom, so we can apply the same equations and principles. The text mentions the Balmer series, which corresponds to transitions to n=2n=2. The Balmer-alpha line, often referred to as the Hydrogen-alpha or Hα line, corresponds to the transition from n=3n=3 to n=2n=2 in hydrogen, and its wavelength is 656 nm. Since the helium ion (He+) behaves similarly to hydrogen in this context, the answer to the problem would also be 656 nm. The emitted photon has a wavelength of 656 nm.arrow_forward
- Which of the following statements related to quantum statistics are true? Select one or more: a.The wave function of a pair of bosons is symmetric with respect to the exchange of particles. b.If the particle density of an ideal gas is very low (that is, the particle density is much less than the cube of the thermal de Broglie wavelength), quantum effects are important. c.In the case of a rare gas and at high enough temperatures, the Fermi-Dirac and Bose-Einstein distributions are approximately the same. d.Two bosons cannot be in the same quantum state.arrow_forwardSolve the following problem: Use rest mass energy of the electron 0.5 MeV Consider an atomic level with quantum numbers n = 2,l = 1 and maximum total angular momentum. a. Find the first order relativistic correction to this level, in electron- volts. b. Find the first order spin-orbit correction to this level, in electron-volts. C. Use your result in parts a and b to find the energy of that level.arrow_forward(a) What is the minimum value of l for a subshell that contains 11 electrons? (b) If this subshell is in the n = 5 shell, what is the spectroscopic notation for this atom?arrow_forward
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