EBK FUNDAMENTALS OF ANALYTICAL CHEMISTR
9th Edition
ISBN: 9780100459908
Author: Holler
Publisher: YUZU
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- Lead poisoning has been a hazard for centuries. Some scholars believe that the decline of the Roman Empire can be traced, in part, to high levels of lead in water from containers and pipes, and from wine that was stored in leadglazed containers. If we presume that the typical Roman water supply was saturated with lead carbonate, PbCO3 (Ksp = 7.4 1014), how much lead will a Roman ingest in a year if he or she drinks 1 L/day from the container?arrow_forwardDescribe in words how you would prepare pure crystalline AgCl and NaNO3 from solid AgNO3 and solid NaCl.arrow_forwardYou are given a solid mixture of NaNO2 and NaCl and are asked to analyze it for the amount of NaNO2 present. To do so, you allow the mixture to react with sulfamic acid, HSO3NH2, in water according to the equation NaNO2(aq) + HSO3NH2(aq) NaHSO4(aq) + H2O() + N2(g) What is the weight percentage of NaNO2 in 1.232 g of the solid mixture if reaction with sulfa-mic acid produces 295 mL of dry N2 gas with a pressure of 713 mm Hg at 21.0 C?arrow_forward
- What is the molarity of a solution of sodium hydrogen sulfate that is prepared by dissolving 9.21 g NaHSO4 in enough water to form 2.00-L solution? What is the molarity of each ion in the solution?arrow_forwardHow would you prepare from the solid and pure water (a) 0.400 L of 0.155 M Sr(OH)2? (b) 1.75 L of 0.333 M (NH4)2CO3?arrow_forwardCalculate the molarity of AgNO3 in a solution prepared by dissolving 1.44 g AgNO3 in enough water to form 1.00 L solution.arrow_forward
- Magnesium metal (a component of alloys used in aircraft and a reducing agent used in the production of uranium, titanium, and other active metals) is isolated from sea water by the following sequence of reactions: Mg2+(aq)+Ca(OH)2(aq)Mg(OH)2(s)+Ca2+(aq)Mg(OH)2(s)+2HCl(aq)MgCl2(s)+2H2O(l)MgCl2(l)electrolysisMg(s)+Cl2+Cl2(g) Sea water has a density of 1.026 g/cm3 and contains 1272 parts per million of magnesium a5 Mg2+(aq) by mass. What mass, in kilograms, of Ca(OH)2; is required to precipitate 99.9% of the magnesium in 1.00103 L of sea water?arrow_forwardA sample of limestone weighing 1.005 g is dissolved in 75.00 mL of 0.2500 M hydrochloric acid. The following reaction occurs: CaCO3(s)+2 H+(aq)Ca2+(aq)+CO2(g)+H2O It is found that 19.26 mL of 0.150 M NaOH is required to titrate the excess HCI left after reaction with the limestone. What is the mass percent of CaCO3 in the limestone?arrow_forwardGold metal will dissolve only in aqua regia, a mixture of concentrated hydrochloric acid and concentrated nitric acid in a 3:1 volume ratio. The products of the reaction between gold and the concentrated acids are AuCl4-(aq), NO(g), and H2O. The equation for this reaction where HNO3 and HCl are strong acids is Au(s)+4Cl(aq)+4H+(aq)+NO3(aq)AuCl4(aq)+NO(g)+2H2O(a) What stoichiometric ratio of hydrochloric acid to nitric acid should be used? (b) What volumes of 12 M HCl and 16 M are HNO3 required to furnish the Cl- and NO3- ions to react with 25.0 g of gold?arrow_forward
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