Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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(a) Identify the functional groups in salinosporamide A, an anticancer agent isolated from marine sediment. (b) Classify each alcohol, alkyl halide, amide, and amine as 1°, 2°, or 3°.
(a) Draw the structures for the eight constitutional isomers of molecular formula C 4H 11N. (b) Give the systematic name for each amine. (c) Identify the chirality center present in one of the amines.
(a) Identify the functional groups in salinosporamide A, an anticanceragent isolated from marine sediment. (b) Classify each alcohol, alkylhalide, amide, and amine as 1°, 2°, or 3°.
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- TRUE OR FALSE (a) There are three amines with the molecular formula C3H9N. (b) Aldehydes, ketones, carboxylic acids, and esters all contain a carbonyl group. (c) A compound with the molecular formula of C3H6O may be either an aldehyde, a ketone, or a carboxylic acid. (d) Bond angles about the carbonyl carbon of an aldehyde, a ketone, a carboxylic acid, and an ester are all approximately 109.5°. (e) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O. (f) The molecular formula of the smallest carboxylic acid is C2H4O2.arrow_forwardDraw the condensed formula or skeletal structural formula for the following compounds: (a) 2,3-dimethylpentanoic acid (b) Ethyl pentanoate (c) N,N-dimethyl-1-propanaminearrow_forwardIndicate whether each statement is true or false: (a) Fat molecules contain amide bonds. (b) Phosphoplipids can be zwitterions. (c) Phospholipids form bilayers in water in order to have their long hydrophobic tails interact favorably with each other, leaving their polar heads to the aqueous environment.arrow_forward
- Compounds that contain an N-H group associate by hydrogen bonding. (a) Do you expect this association to be stronger or weaker than that of compounds containing an O-H group? (b) Based on your answer to part (a), which would you predict to have the higher boiling point, 1-butanol or 1-butanamine?arrow_forwardDraw the structures of the following compounds:(a) Ethanoic acid(b) Bromopentane(c) Butanonearrow_forwardMaleic acid and fumaric acid are the cis- and trans- isomers, respectively, of C2H2(COOH)2, a dicarboxylic acid. Draw and label their structures.arrow_forward
- Sphingomyelins, a group of lipids that resemble the membrane phospholipids discussed in Section 3.7, are a major component of the myelin sheath, the insulating layer that surrounds a nerve fiber. (A) What functional groups are present in sphingomyelin X? (B) Classify any alcohol, amine, and amide as 1, 2, or 3. (C) Label the polar head and non polar tails of X.arrow_forwardIn each of the following reactions, two possible organic products can be formed. Draw both organic products in each case and then circle the one formed in greatest quantity in each case. HC (a) 1) NaH, 2) acid (b) CH,CH,OH (c) CH,CH,OH NH2 (d) Oarrow_forwardWrite the products of the following acid-base reactions: (a) CH3OH + H2SO4 ² ? (b) CH3OH + NANH2 2 ? (c) CH3NH3+ Cl- + NaOH ?arrow_forward
- Identify which of the statements is/are correct. (i) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O. (j) The molecular formula of the smallest carboxylic acid is C2H4O2.arrow_forwardWrite equations to show how the following compounds are oxidized by (1) K2Cr2O7 + H2SO4, (2) Cu2+, or Ag+: (a) 1-propanol (b) 2,3-dimethyl-2-butanolarrow_forwardWhat type of product should be formed if butanol went through an oxidation reaction to completion? (A) carboxylic acid (B) ketone (C) no product formed (D) aldehydearrow_forward
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