EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Draw the conjugate base and rank the compounds in order of increasing acidity. Explain the reason briefly
a) Draw the conjugate base formed when the following compound is deprotonated.
b) Rank the following from strongest acid to weakest acid:
Which of the following anions is the stronger base? Explain your choice by typing your answer
below.
A
В
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- Answer true or false to the following statements about the mechanism of acid-base reactions. (a) The acid and base must encounter each other by a collision in order for the proton to transfer. (b) All collisions between acids and bases result in proton transfer. (c) During an acid-base reaction the lone pair on the base fills the A-H antibonding sigma orbital.arrow_forwardAs we shall see in Chapter 19, hydrogens on a carbon adjacent to a carbonyl group are far more acidic than those not adjacent to a carbonyl group. The anion derived from acetone, for example, is more stable than is the anion derived from ethane. Account for the greater stability of the anion from acetone.arrow_forwardThe following reactions illustrate Brnsted acid-base behavior. Complete each equation. a.HI(aq)+?H3O+(aq)+I(aq) b.NH3(l)+?NH4++NH2 c.H2C2O4(aq)+H2O(l)?+HC2O4(aq) d.H2N2O2(aq)+H2O(l)H3O+(aq)+? e.?+H2O(l)H3O+(aq)+CO32(aq)arrow_forward
- Match each species with its correct description. fluoride (F-) water (H2O) ammonia (NH3) hydrogen sulfate (HSO4-) nitric acid (HNO3) methylaminium (CH3NH3+) Answer choices: its conjugate base is OH is the conjugate acid of CH3NH2 is the conjugate base of NO3- its conjugate base is NO3- is the conjugate base of sulfate (SO4 2-) its conjugate base is CH3NH- is the conjugate base of HF is the conjugate acid of NH2- its conjugate acid is H3O+ its conjugate acid is HF+ is the conjugate base of NH4 its conjugate acid is H2SO4arrow_forwardWhat is the role of ammonium ion in the following reaction? NH3 H;0 H20 NHA + Select one: Conjugate acid Acid Conjugate base Basearrow_forwardLabel each reactant and product in this reaction as a Brønsted acid or base. CH, OH + OH¯ = CH,O¯ + H,O Answer Bank acid basearrow_forward
- Which of the following anions is the stronger base? Explain your choice by typing your answer below. Aarrow_forwardPlace the following in order of increasing basicityarrow_forwardPart B Rank the following compound from strongest acid to weakest. To rank items as equivalent, overlap them. Strongest Submit The correct ranking cannot be determined. Previous Answers Request Answer acetic acid dichloroacetic acid methylsulfonic acid Reset Help Weakestarrow_forward
- Predict the position of the equilibrium for the reaction and provide a brief explanation. (The acidic protons are shown in red.) F3C F3C OH F3C ČF3 F3C ČF3 A В Reverse direction is favored because the fluorine atoms stabilize B via inductive effects, making B the weaker base and D the stronger acid. Forward direction is favored because the fluorine atoms stabilize B via inductive effects, making B the stronger base and D the weaker acid. Forward direction is favored because the fluorine atoms stabilize B via inductive effects, making B the weaker base and D the stronger acid. Reverse direction is favored because the fluorine atoms stabilize B via inductive effects, making B the stronger base and D the weaker acid.arrow_forwardDraw the most stable conjugate base and most stable conjugate acids for the following compounds. H₂N F2 Н ² OH CO,H НО ОН НО ОН НОarrow_forward
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