Connect Online Access 1-Semester for Organic Chemistry
6th Edition
ISBN: 9781260475609
Author: SMITH, Janice
Publisher: Mcgraw-hill Higher Education (us)
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Textbook Question
Chapter 29, Problem 41P
Draw the products formed when cholesterol is treated with each reagent. Indicate the stereochemistry around any stereogenic centers in the product.
a.
b.
c. PCC
d. oleic acid,
e. [1]
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Please explain the mechanisms/steps
Draw the product formed when pentanal (CH;CH,CH2CH;CHO) is treated with each reagent. With some reagents, no reaction
occurs.
a. NaBH4, CH,OH
b. [1] LIAIH4; (2] H20
c. H2, Pd-C
d. PCC
e. NazCr,07, H2SO4, H2O
f. Ag,0, NH,OH
g. [1) CH,MgBr; (2] H2O
h. [1] CęH,Li; [2] H20
i. [1] (CH3),CuLi; (2] H2O
j. [1] HC=CNa; [2] H2O
k. [1] CH;C=CLi; [2] H2O
I. The product in (a), then TBDMS-CI, imidazole
3. What product is formed when HO(CH₂) CHO is treated with each reagent?
c. Ag₂O, NH OH
d. Na₂Cr₂O₂, H₂SO4, H₂O
a. NaBH, CH₂OH
b. PCC
400
Chapter 29 Solutions
Connect Online Access 1-Semester for Organic Chemistry
Ch. 29.2 - Problem 31.1
One component of jojoba oil is a wax...Ch. 29.3 - Problem 31.2
How would you expect the melting...Ch. 29.3 - Problem 31.3
Draw the products formed when...Ch. 29.3 - Problem 31.4
The main fatty acid component of the...Ch. 29.3 - Prob. 5PCh. 29.7 - Problem 31.10
Locate the isoprene units in each...Ch. 29.7 - Problem 31.11
Locate the isoprene units in...Ch. 29.7 - Problem 31.12
Write a stepwise mechanism for the...Ch. 29.7 - Prob. 14PCh. 29.8 - Prob. 15P
Ch. 29.8 - Prob. 16PCh. 29.8 - Prob. 17PCh. 29 - 31.17 Locate the isoprene units in each...Ch. 29 - Prob. 25PCh. 29 - Locate the isoprene units in each compound. a. e....Ch. 29 - 31.27 Classify each terpene and terpenoid in...Ch. 29 - Prob. 33PCh. 29 - Draw three-dimensional structures f or each...Ch. 29 - Prob. 37PCh. 29 - Prob. 38PCh. 29 - Prob. 39PCh. 29 - Prob. 40PCh. 29 - 31.38 Draw the products formed when cholesterol is...Ch. 29 - 31.39 Draw a stepwise mechanism for the following...Ch. 29 - 31.40 Draw a stepwise mechanism for the following...Ch. 29 - Prob. 44P
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- Draw the organic product(s) formed when CH3CH2CH2OH is treated with each reagent. a.H2SO4 b.NaH c.HCl + ZnCl2 d.HBr e.SOCl2, pyridine f.PBr3 g.TsCl, pyridine h. [1] NaH; [2] CH3CH2Br [1] i.TsCl, pyridine; [2] NaSH j.POCl3, pyridinearrow_forwarda. In an aqueous solution, d-glucose exists in equilibrium with two six-membered ring compounds. Draw the structures of these compounds.b. Which of the six-membered ring compounds will be the major product?arrow_forwardDetermine the product formed when butanone (CH3CH,COCH3) Is treated with each reagent. If no reaction occurs, label the reaction with "no reaction". PCC H2 Pd-C HO OH NazCr,O, H,SO.H,O [1] LIAIH, [2] H,O no reaction Ag20 NH,OH NABH, CH;OH Resetarrow_forward
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